4,4′-[Propane-1,2-diyl­bis(nitrilo­methyl­idyne)]­dibenzo­nitrile–4,4′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]dibenzonitrile [0.796 (2)/0.204 (2)]

The title cocrystal, 0.796C(19)H(16)N(4)·0.204C(18)H(14)N(4), is a disordered mixture of two potentially bidentate Schiff base ligands. The difference in the two components of the cocrystal is the replacement of the methyl group in the linkage between the imine N atoms in the major component of the...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kia, Reza, Kargar, Hadi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959562/
https://www.ncbi.nlm.nih.gov/pubmed/21580986
http://dx.doi.org/10.1107/S1600536808031097
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author Fun, Hoong-Kun
Kia, Reza
Kargar, Hadi
author_facet Fun, Hoong-Kun
Kia, Reza
Kargar, Hadi
author_sort Fun, Hoong-Kun
collection PubMed
description The title cocrystal, 0.796C(19)H(16)N(4)·0.204C(18)H(14)N(4), is a disordered mixture of two potentially bidentate Schiff base ligands. The difference in the two components of the cocrystal is the replacement of the methyl group in the linkage between the imine N atoms in the major component of the Schiff base ligand by an H atom. The imino (C=N) functional groups are coplanar with the benzene rings (only the major component) and extend in opposite directions (both components). Inter­molecular π–π inter­actions with a centroid-to-centroid distance of 3.7371 (8) Å are observed in the crystal packing.
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spelling pubmed-29595622010-12-30 4,4′-[Propane-1,2-diyl­bis(nitrilo­methyl­idyne)]­dibenzo­nitrile–4,4′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]dibenzonitrile [0.796 (2)/0.204 (2)] Fun, Hoong-Kun Kia, Reza Kargar, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title cocrystal, 0.796C(19)H(16)N(4)·0.204C(18)H(14)N(4), is a disordered mixture of two potentially bidentate Schiff base ligands. The difference in the two components of the cocrystal is the replacement of the methyl group in the linkage between the imine N atoms in the major component of the Schiff base ligand by an H atom. The imino (C=N) functional groups are coplanar with the benzene rings (only the major component) and extend in opposite directions (both components). Inter­molecular π–π inter­actions with a centroid-to-centroid distance of 3.7371 (8) Å are observed in the crystal packing. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959562/ /pubmed/21580986 http://dx.doi.org/10.1107/S1600536808031097 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Kia, Reza
Kargar, Hadi
4,4′-[Propane-1,2-diyl­bis(nitrilo­methyl­idyne)]­dibenzo­nitrile–4,4′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]dibenzonitrile [0.796 (2)/0.204 (2)]
title 4,4′-[Propane-1,2-diyl­bis(nitrilo­methyl­idyne)]­dibenzo­nitrile–4,4′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]dibenzonitrile [0.796 (2)/0.204 (2)]
title_full 4,4′-[Propane-1,2-diyl­bis(nitrilo­methyl­idyne)]­dibenzo­nitrile–4,4′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]dibenzonitrile [0.796 (2)/0.204 (2)]
title_fullStr 4,4′-[Propane-1,2-diyl­bis(nitrilo­methyl­idyne)]­dibenzo­nitrile–4,4′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]dibenzonitrile [0.796 (2)/0.204 (2)]
title_full_unstemmed 4,4′-[Propane-1,2-diyl­bis(nitrilo­methyl­idyne)]­dibenzo­nitrile–4,4′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]dibenzonitrile [0.796 (2)/0.204 (2)]
title_short 4,4′-[Propane-1,2-diyl­bis(nitrilo­methyl­idyne)]­dibenzo­nitrile–4,4′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]dibenzonitrile [0.796 (2)/0.204 (2)]
title_sort 4,4′-[propane-1,2-diyl­bis(nitrilo­methyl­idyne)]­dibenzo­nitrile–4,4′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]dibenzonitrile [0.796 (2)/0.204 (2)]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959562/
https://www.ncbi.nlm.nih.gov/pubmed/21580986
http://dx.doi.org/10.1107/S1600536808031097
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AT kiareza 44propane12diylbisnitrilomethylidynedibenzonitrile44ethane12diylbisnitrilomethylidynedibenzonitrile0796202042
AT kargarhadi 44propane12diylbisnitrilomethylidynedibenzonitrile44ethane12diylbisnitrilomethylidynedibenzonitrile0796202042

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