Bostrycin

The title compound, C(16)H(16)O(8), is a potent nonspecific phyto­toxin. The crystal structure is the average of two tauto­mers, 5,6,7,9,10-penta­hydr­oxy-2-meth­oxy-7-methyl-1,4,5,6,7,8-hexa­hydro­anthracene-1,4-dione and 1,4,5,6,7-pentahydr­oxy-2-meth­­oxy-7-methyl-5,6,7,8,9,10-hexa­hydro­anthrace...

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Detalles Bibliográficos
Autores principales: Chen, Shao-Yuan, Huang, Chao, Zhang, Chu-Long, Chen, Yu-Zhe, Lin, Fu-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959567/
https://www.ncbi.nlm.nih.gov/pubmed/21581081
http://dx.doi.org/10.1107/S1600536808032030
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author Chen, Shao-Yuan
Huang, Chao
Zhang, Chu-Long
Chen, Yu-Zhe
Lin, Fu-Cheng
author_facet Chen, Shao-Yuan
Huang, Chao
Zhang, Chu-Long
Chen, Yu-Zhe
Lin, Fu-Cheng
author_sort Chen, Shao-Yuan
collection PubMed
description The title compound, C(16)H(16)O(8), is a potent nonspecific phyto­toxin. The crystal structure is the average of two tauto­mers, 5,6,7,9,10-penta­hydr­oxy-2-meth­oxy-7-methyl-1,4,5,6,7,8-hexa­hydro­anthracene-1,4-dione and 1,4,5,6,7-pentahydr­oxy-2-meth­­oxy-7-methyl-5,6,7,8,9,10-hexa­hydro­anthracene-9,10-di­one. The cyclo­hexene rings in both tautomers display a half-chair conformation. An extensive O—H⋯O hydrogen-bonding network is present in the crystal structure.
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spelling pubmed-29595672010-12-30 Bostrycin Chen, Shao-Yuan Huang, Chao Zhang, Chu-Long Chen, Yu-Zhe Lin, Fu-Cheng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(16)O(8), is a potent nonspecific phyto­toxin. The crystal structure is the average of two tauto­mers, 5,6,7,9,10-penta­hydr­oxy-2-meth­oxy-7-methyl-1,4,5,6,7,8-hexa­hydro­anthracene-1,4-dione and 1,4,5,6,7-pentahydr­oxy-2-meth­­oxy-7-methyl-5,6,7,8,9,10-hexa­hydro­anthracene-9,10-di­one. The cyclo­hexene rings in both tautomers display a half-chair conformation. An extensive O—H⋯O hydrogen-bonding network is present in the crystal structure. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959567/ /pubmed/21581081 http://dx.doi.org/10.1107/S1600536808032030 Text en © Chen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chen, Shao-Yuan
Huang, Chao
Zhang, Chu-Long
Chen, Yu-Zhe
Lin, Fu-Cheng
Bostrycin
title Bostrycin
title_full Bostrycin
title_fullStr Bostrycin
title_full_unstemmed Bostrycin
title_short Bostrycin
title_sort bostrycin
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959567/
https://www.ncbi.nlm.nih.gov/pubmed/21581081
http://dx.doi.org/10.1107/S1600536808032030
work_keys_str_mv AT chenshaoyuan bostrycin
AT huangchao bostrycin
AT zhangchulong bostrycin
AT chenyuzhe bostrycin
AT linfucheng bostrycin

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