[2,6-Bis(di-tert-butyl­phosphinometh­yl)­phen­yl-κ(3) P,C (1),P′](nitrato-κO)nickel(II)

The Ni(II) atom in the title compound, [Ni(C(24)H(43)P(2))(NO(3))], adopts a distorted square-planar geometry with the P atoms in a trans arrangement. The compound contains a twofold rotational axis with the nitrate group offset from this axis, except for an O atom of the nitrate group, generating t...

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Detalles Bibliográficos
Autores principales: Boro, Brian J., Dickie, Diane A., Duesler, Eileen N., Goldberg, Karen I., Kemp, Richard A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959575/
https://www.ncbi.nlm.nih.gov/pubmed/21580852
http://dx.doi.org/10.1107/S1600536808032376
Descripción
Sumario:The Ni(II) atom in the title compound, [Ni(C(24)H(43)P(2))(NO(3))], adopts a distorted square-planar geometry with the P atoms in a trans arrangement. The compound contains a twofold rotational axis with the nitrate group offset from this axis, except for an O atom of the nitrate group, generating two positions of 50% occupancy for the other atoms of the nitrate group.

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