[2,6-Bis(di-tert-butyl­phosphinometh­yl)­phen­yl-κ(3) P,C (1),P′](nitrato-κO)nickel(II)

The Ni(II) atom in the title compound, [Ni(C(24)H(43)P(2))(NO(3))], adopts a distorted square-planar geometry with the P atoms in a trans arrangement. The compound contains a twofold rotational axis with the nitrate group offset from this axis, except for an O atom of the nitrate group, generating t...

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Detalles Bibliográficos
Autores principales: Boro, Brian J., Dickie, Diane A., Duesler, Eileen N., Goldberg, Karen I., Kemp, Richard A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959575/
https://www.ncbi.nlm.nih.gov/pubmed/21580852
http://dx.doi.org/10.1107/S1600536808032376
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author Boro, Brian J.
Dickie, Diane A.
Duesler, Eileen N.
Goldberg, Karen I.
Kemp, Richard A.
author_facet Boro, Brian J.
Dickie, Diane A.
Duesler, Eileen N.
Goldberg, Karen I.
Kemp, Richard A.
author_sort Boro, Brian J.
collection PubMed
description The Ni(II) atom in the title compound, [Ni(C(24)H(43)P(2))(NO(3))], adopts a distorted square-planar geometry with the P atoms in a trans arrangement. The compound contains a twofold rotational axis with the nitrate group offset from this axis, except for an O atom of the nitrate group, generating two positions of 50% occupancy for the other atoms of the nitrate group.
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spelling pubmed-29595752010-12-30 [2,6-Bis(di-tert-butyl­phosphinometh­yl)­phen­yl-κ(3) P,C (1),P′](nitrato-κO)nickel(II) Boro, Brian J. Dickie, Diane A. Duesler, Eileen N. Goldberg, Karen I. Kemp, Richard A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni(II) atom in the title compound, [Ni(C(24)H(43)P(2))(NO(3))], adopts a distorted square-planar geometry with the P atoms in a trans arrangement. The compound contains a twofold rotational axis with the nitrate group offset from this axis, except for an O atom of the nitrate group, generating two positions of 50% occupancy for the other atoms of the nitrate group. International Union of Crystallography 2008-10-15 /pmc/articles/PMC2959575/ /pubmed/21580852 http://dx.doi.org/10.1107/S1600536808032376 Text en © Boro et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Boro, Brian J.
Dickie, Diane A.
Duesler, Eileen N.
Goldberg, Karen I.
Kemp, Richard A.
[2,6-Bis(di-tert-butyl­phosphinometh­yl)­phen­yl-κ(3) P,C (1),P′](nitrato-κO)nickel(II)
title [2,6-Bis(di-tert-butyl­phosphinometh­yl)­phen­yl-κ(3) P,C (1),P′](nitrato-κO)nickel(II)
title_full [2,6-Bis(di-tert-butyl­phosphinometh­yl)­phen­yl-κ(3) P,C (1),P′](nitrato-κO)nickel(II)
title_fullStr [2,6-Bis(di-tert-butyl­phosphinometh­yl)­phen­yl-κ(3) P,C (1),P′](nitrato-κO)nickel(II)
title_full_unstemmed [2,6-Bis(di-tert-butyl­phosphinometh­yl)­phen­yl-κ(3) P,C (1),P′](nitrato-κO)nickel(II)
title_short [2,6-Bis(di-tert-butyl­phosphinometh­yl)­phen­yl-κ(3) P,C (1),P′](nitrato-κO)nickel(II)
title_sort [2,6-bis(di-tert-butyl­phosphinometh­yl)­phen­yl-κ(3) p,c (1),p′](nitrato-κo)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959575/
https://www.ncbi.nlm.nih.gov/pubmed/21580852
http://dx.doi.org/10.1107/S1600536808032376
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