Poly[[diaqua-μ(2)-hydroxido-(μ(7)-2-phos­pho­nato­ethane­sulfonato)­dicopper(II)] trihydrate]

The crystal structure of the title compound, [Cu(2)(C(2)H(4)O(6)PS)(OH)(H(2)O)(2)]·3H(2)O, consists of two Cu(2+) ions, one (O(3)PC(2)H(4)SO(3))(3−) ion and one OH(−) ion, as well as five water mol­ecules, two of which are coordinated to Cu(2+). The Cu(2+) ions are coordinated by six O atoms. The Cu...

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Detalles Bibliográficos
Autores principales: Sonnauer, Andreas, Lieb, Alexandra, Stock, Norbert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959580/
https://www.ncbi.nlm.nih.gov/pubmed/21580864
http://dx.doi.org/10.1107/S1600536808033229
Descripción
Sumario:The crystal structure of the title compound, [Cu(2)(C(2)H(4)O(6)PS)(OH)(H(2)O)(2)]·3H(2)O, consists of two Cu(2+) ions, one (O(3)PC(2)H(4)SO(3))(3−) ion and one OH(−) ion, as well as five water mol­ecules, two of which are coordinated to Cu(2+). The Cu(2+) ions are coordinated by six O atoms. The CuO(6) polyhedra are connected by μ- and μ(3)-O atoms into zigzag chains along the b axis. These chains are further connected by –CH(2)CH(2)– groups to form layers, in turn building a three-dimensional framework via hydrogen bonding.

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