Poly[[diaqua-μ(2)-hydroxido-(μ(7)-2-phos­pho­nato­ethane­sulfonato)­dicopper(II)] trihydrate]

The crystal structure of the title compound, [Cu(2)(C(2)H(4)O(6)PS)(OH)(H(2)O)(2)]·3H(2)O, consists of two Cu(2+) ions, one (O(3)PC(2)H(4)SO(3))(3−) ion and one OH(−) ion, as well as five water mol­ecules, two of which are coordinated to Cu(2+). The Cu(2+) ions are coordinated by six O atoms. The Cu...

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Detalles Bibliográficos
Autores principales: Sonnauer, Andreas, Lieb, Alexandra, Stock, Norbert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959580/
https://www.ncbi.nlm.nih.gov/pubmed/21580864
http://dx.doi.org/10.1107/S1600536808033229
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author Sonnauer, Andreas
Lieb, Alexandra
Stock, Norbert
author_facet Sonnauer, Andreas
Lieb, Alexandra
Stock, Norbert
author_sort Sonnauer, Andreas
collection PubMed
description The crystal structure of the title compound, [Cu(2)(C(2)H(4)O(6)PS)(OH)(H(2)O)(2)]·3H(2)O, consists of two Cu(2+) ions, one (O(3)PC(2)H(4)SO(3))(3−) ion and one OH(−) ion, as well as five water mol­ecules, two of which are coordinated to Cu(2+). The Cu(2+) ions are coordinated by six O atoms. The CuO(6) polyhedra are connected by μ- and μ(3)-O atoms into zigzag chains along the b axis. These chains are further connected by –CH(2)CH(2)– groups to form layers, in turn building a three-dimensional framework via hydrogen bonding.
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spelling pubmed-29595802010-12-30 Poly[[diaqua-μ(2)-hydroxido-(μ(7)-2-phos­pho­nato­ethane­sulfonato)­dicopper(II)] trihydrate] Sonnauer, Andreas Lieb, Alexandra Stock, Norbert Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Cu(2)(C(2)H(4)O(6)PS)(OH)(H(2)O)(2)]·3H(2)O, consists of two Cu(2+) ions, one (O(3)PC(2)H(4)SO(3))(3−) ion and one OH(−) ion, as well as five water mol­ecules, two of which are coordinated to Cu(2+). The Cu(2+) ions are coordinated by six O atoms. The CuO(6) polyhedra are connected by μ- and μ(3)-O atoms into zigzag chains along the b axis. These chains are further connected by –CH(2)CH(2)– groups to form layers, in turn building a three-dimensional framework via hydrogen bonding. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959580/ /pubmed/21580864 http://dx.doi.org/10.1107/S1600536808033229 Text en © Sonnauer et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sonnauer, Andreas
Lieb, Alexandra
Stock, Norbert
Poly[[diaqua-μ(2)-hydroxido-(μ(7)-2-phos­pho­nato­ethane­sulfonato)­dicopper(II)] trihydrate]
title Poly[[diaqua-μ(2)-hydroxido-(μ(7)-2-phos­pho­nato­ethane­sulfonato)­dicopper(II)] trihydrate]
title_full Poly[[diaqua-μ(2)-hydroxido-(μ(7)-2-phos­pho­nato­ethane­sulfonato)­dicopper(II)] trihydrate]
title_fullStr Poly[[diaqua-μ(2)-hydroxido-(μ(7)-2-phos­pho­nato­ethane­sulfonato)­dicopper(II)] trihydrate]
title_full_unstemmed Poly[[diaqua-μ(2)-hydroxido-(μ(7)-2-phos­pho­nato­ethane­sulfonato)­dicopper(II)] trihydrate]
title_short Poly[[diaqua-μ(2)-hydroxido-(μ(7)-2-phos­pho­nato­ethane­sulfonato)­dicopper(II)] trihydrate]
title_sort poly[[diaqua-μ(2)-hydroxido-(μ(7)-2-phos­pho­nato­ethane­sulfonato)­dicopper(ii)] trihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959580/
https://www.ncbi.nlm.nih.gov/pubmed/21580864
http://dx.doi.org/10.1107/S1600536808033229
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AT stocknorbert polydiaquam2hydroxidom72phosphonatoethanesulfonatodicopperiitrihydrate

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