Bis(N,N-dimethyl­formamide-κO)bis­(1-methyl­imidazole-2-carbaldehyde oximato-κ(2) N,O)manganese(III) perchlorate

In the title compound, [Mn(C(5)H(6)N(3)O)(2)(C(3)H(7)NO)]ClO(4), the Mn(III) atom lies on the inversion centre of the centrosymmetric complex cation and has a distorted octa­hedral coordination geometry, formed by two N atoms and two O atoms from two 1-methyl­imidazole-2-carbaldehyde oximate ligands...

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Detalles Bibliográficos
Autores principales: Wang, Feng, Zhang, Jianming, Wang, Qirong, Huang, Shiying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959584/
https://www.ncbi.nlm.nih.gov/pubmed/21580900
http://dx.doi.org/10.1107/S1600536808034016
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author Wang, Feng
Zhang, Jianming
Wang, Qirong
Huang, Shiying
author_facet Wang, Feng
Zhang, Jianming
Wang, Qirong
Huang, Shiying
author_sort Wang, Feng
collection PubMed
description In the title compound, [Mn(C(5)H(6)N(3)O)(2)(C(3)H(7)NO)]ClO(4), the Mn(III) atom lies on the inversion centre of the centrosymmetric complex cation and has a distorted octa­hedral coordination geometry, formed by two N atoms and two O atoms from two 1-methyl­imidazole-2-carbaldehyde oximate ligands and two O atoms from two dimethyl­formamide ligands. Perchlorate acts as a counterion to balance the charge. The crystal structure of the title compound is stabilized by C—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-29595842010-12-30 Bis(N,N-dimethyl­formamide-κO)bis­(1-methyl­imidazole-2-carbaldehyde oximato-κ(2) N,O)manganese(III) perchlorate Wang, Feng Zhang, Jianming Wang, Qirong Huang, Shiying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(5)H(6)N(3)O)(2)(C(3)H(7)NO)]ClO(4), the Mn(III) atom lies on the inversion centre of the centrosymmetric complex cation and has a distorted octa­hedral coordination geometry, formed by two N atoms and two O atoms from two 1-methyl­imidazole-2-carbaldehyde oximate ligands and two O atoms from two dimethyl­formamide ligands. Perchlorate acts as a counterion to balance the charge. The crystal structure of the title compound is stabilized by C—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2008-10-25 /pmc/articles/PMC2959584/ /pubmed/21580900 http://dx.doi.org/10.1107/S1600536808034016 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Feng
Zhang, Jianming
Wang, Qirong
Huang, Shiying
Bis(N,N-dimethyl­formamide-κO)bis­(1-methyl­imidazole-2-carbaldehyde oximato-κ(2) N,O)manganese(III) perchlorate
title Bis(N,N-dimethyl­formamide-κO)bis­(1-methyl­imidazole-2-carbaldehyde oximato-κ(2) N,O)manganese(III) perchlorate
title_full Bis(N,N-dimethyl­formamide-κO)bis­(1-methyl­imidazole-2-carbaldehyde oximato-κ(2) N,O)manganese(III) perchlorate
title_fullStr Bis(N,N-dimethyl­formamide-κO)bis­(1-methyl­imidazole-2-carbaldehyde oximato-κ(2) N,O)manganese(III) perchlorate
title_full_unstemmed Bis(N,N-dimethyl­formamide-κO)bis­(1-methyl­imidazole-2-carbaldehyde oximato-κ(2) N,O)manganese(III) perchlorate
title_short Bis(N,N-dimethyl­formamide-κO)bis­(1-methyl­imidazole-2-carbaldehyde oximato-κ(2) N,O)manganese(III) perchlorate
title_sort bis(n,n-dimethyl­formamide-κo)bis­(1-methyl­imidazole-2-carbaldehyde oximato-κ(2) n,o)manganese(iii) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959584/
https://www.ncbi.nlm.nih.gov/pubmed/21580900
http://dx.doi.org/10.1107/S1600536808034016
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