Dicarbon­yl(η(5)-cyclo­penta­dien­yl)bis­(trimethyl­phosphine)molybdenum(II) trifluoro­methane­sulfonate

In the title compound, [Mo(C(5)H(5))(CO)(2)(C(3)H(9)P)(2)]CF(3)SO(3), the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a trans configuration of the basal ligands around the Mo atom. The cyclo­penta­dienyl (Cp) ligand occupies the apical position of the...

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Detalles Bibliográficos
Autores principales: Jali, Samuel, Friedrich, Holger B., Bala, Muhammad D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959586/
https://www.ncbi.nlm.nih.gov/pubmed/21580851
http://dx.doi.org/10.1107/S1600536808032662
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author Jali, Samuel
Friedrich, Holger B.
Bala, Muhammad D.
author_facet Jali, Samuel
Friedrich, Holger B.
Bala, Muhammad D.
author_sort Jali, Samuel
collection PubMed
description In the title compound, [Mo(C(5)H(5))(CO)(2)(C(3)H(9)P)(2)]CF(3)SO(3), the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a trans configuration of the basal ligands around the Mo atom. The cyclo­penta­dienyl (Cp) ligand occupies the apical position of the piano-stool configuration. The average Mo—P bond length of the two trans PMe(3) ligands is 2.474 (5) Å and the Mo—Cp centroid distance is 2.003 (2) Å.
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spelling pubmed-29595862010-12-30 Dicarbon­yl(η(5)-cyclo­penta­dien­yl)bis­(trimethyl­phosphine)molybdenum(II) trifluoro­methane­sulfonate Jali, Samuel Friedrich, Holger B. Bala, Muhammad D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mo(C(5)H(5))(CO)(2)(C(3)H(9)P)(2)]CF(3)SO(3), the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a trans configuration of the basal ligands around the Mo atom. The cyclo­penta­dienyl (Cp) ligand occupies the apical position of the piano-stool configuration. The average Mo—P bond length of the two trans PMe(3) ligands is 2.474 (5) Å and the Mo—Cp centroid distance is 2.003 (2) Å. International Union of Crystallography 2008-10-15 /pmc/articles/PMC2959586/ /pubmed/21580851 http://dx.doi.org/10.1107/S1600536808032662 Text en © Jali et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jali, Samuel
Friedrich, Holger B.
Bala, Muhammad D.
Dicarbon­yl(η(5)-cyclo­penta­dien­yl)bis­(trimethyl­phosphine)molybdenum(II) trifluoro­methane­sulfonate
title Dicarbon­yl(η(5)-cyclo­penta­dien­yl)bis­(trimethyl­phosphine)molybdenum(II) trifluoro­methane­sulfonate
title_full Dicarbon­yl(η(5)-cyclo­penta­dien­yl)bis­(trimethyl­phosphine)molybdenum(II) trifluoro­methane­sulfonate
title_fullStr Dicarbon­yl(η(5)-cyclo­penta­dien­yl)bis­(trimethyl­phosphine)molybdenum(II) trifluoro­methane­sulfonate
title_full_unstemmed Dicarbon­yl(η(5)-cyclo­penta­dien­yl)bis­(trimethyl­phosphine)molybdenum(II) trifluoro­methane­sulfonate
title_short Dicarbon­yl(η(5)-cyclo­penta­dien­yl)bis­(trimethyl­phosphine)molybdenum(II) trifluoro­methane­sulfonate
title_sort dicarbon­yl(η(5)-cyclo­penta­dien­yl)bis­(trimethyl­phosphine)molybdenum(ii) trifluoro­methane­sulfonate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959586/
https://www.ncbi.nlm.nih.gov/pubmed/21580851
http://dx.doi.org/10.1107/S1600536808032662
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AT friedrichholgerb dicarbonylē5cyclopentadienylbistrimethylphosphinemolybdenumiitrifluoromethanesulfonate
AT balamuhammadd dicarbonylē5cyclopentadienylbistrimethylphosphinemolybdenumiitrifluoromethanesulfonate

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