Bis[1-(2,6-dichloro­benz­yl)-3-methyl­pyrazin-1-ium] bis­(maleonitrile­dithiol­ato)nickelate(II)

In the crystal structure of the title compound, (C(12)H(11)Cl(2)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) complex dianion is located on an inversion centre. The Ni(II) atom is coordinated by four S atoms in a square-planar geometry. In the cation, the dihedral angle between the benzene and pyrazine...

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Detalles Bibliográficos
Autores principales: Yu, Shan-Shan, Xian, Hua, Tian, Zheng-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959589/
https://www.ncbi.nlm.nih.gov/pubmed/21580883
http://dx.doi.org/10.1107/S1600536808034776
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author Yu, Shan-Shan
Xian, Hua
Tian, Zheng-Fang
author_facet Yu, Shan-Shan
Xian, Hua
Tian, Zheng-Fang
author_sort Yu, Shan-Shan
collection PubMed
description In the crystal structure of the title compound, (C(12)H(11)Cl(2)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) complex dianion is located on an inversion centre. The Ni(II) atom is coordinated by four S atoms in a square-planar geometry. In the cation, the dihedral angle between the benzene and pyrazine rings is 85.2 (2)°.
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spelling pubmed-29595892010-12-30 Bis[1-(2,6-dichloro­benz­yl)-3-methyl­pyrazin-1-ium] bis­(maleonitrile­dithiol­ato)nickelate(II) Yu, Shan-Shan Xian, Hua Tian, Zheng-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, (C(12)H(11)Cl(2)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) complex dianion is located on an inversion centre. The Ni(II) atom is coordinated by four S atoms in a square-planar geometry. In the cation, the dihedral angle between the benzene and pyrazine rings is 85.2 (2)°. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959589/ /pubmed/21580883 http://dx.doi.org/10.1107/S1600536808034776 Text en © Yu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Shan-Shan
Xian, Hua
Tian, Zheng-Fang
Bis[1-(2,6-dichloro­benz­yl)-3-methyl­pyrazin-1-ium] bis­(maleonitrile­dithiol­ato)nickelate(II)
title Bis[1-(2,6-dichloro­benz­yl)-3-methyl­pyrazin-1-ium] bis­(maleonitrile­dithiol­ato)nickelate(II)
title_full Bis[1-(2,6-dichloro­benz­yl)-3-methyl­pyrazin-1-ium] bis­(maleonitrile­dithiol­ato)nickelate(II)
title_fullStr Bis[1-(2,6-dichloro­benz­yl)-3-methyl­pyrazin-1-ium] bis­(maleonitrile­dithiol­ato)nickelate(II)
title_full_unstemmed Bis[1-(2,6-dichloro­benz­yl)-3-methyl­pyrazin-1-ium] bis­(maleonitrile­dithiol­ato)nickelate(II)
title_short Bis[1-(2,6-dichloro­benz­yl)-3-methyl­pyrazin-1-ium] bis­(maleonitrile­dithiol­ato)nickelate(II)
title_sort bis[1-(2,6-dichloro­benz­yl)-3-methyl­pyrazin-1-ium] bis­(maleonitrile­dithiol­ato)nickelate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959589/
https://www.ncbi.nlm.nih.gov/pubmed/21580883
http://dx.doi.org/10.1107/S1600536808034776
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AT xianhua bis126dichlorobenzyl3methylpyrazin1iumbismaleonitriledithiolatonickelateii
AT tianzhengfang bis126dichlorobenzyl3methylpyrazin1iumbismaleonitriledithiolatonickelateii

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