{N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(trifluoro­methane­sulfanato-κO)copper(II)

A discrete neutral Cu(II) complex, [Cu(CF(3)SO(3))(2)(C(16)H(18)N(4))], has been derived from the symmetrical tetra­dentate Schiff base, N,N′-bis­[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine. The copper centre assumes a tetra­gonally distorted pseudo-octa­hedral geometry with the O atoms of two t...

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Detalles Bibliográficos
Autores principales: Coles, Simon J., Sengul, Abdurrahman, Kurt, Ozgur, Altin, Safinaz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959593/
https://www.ncbi.nlm.nih.gov/pubmed/21580878
http://dx.doi.org/10.1107/S1600536808033151
Descripción
Sumario:A discrete neutral Cu(II) complex, [Cu(CF(3)SO(3))(2)(C(16)H(18)N(4))], has been derived from the symmetrical tetra­dentate Schiff base, N,N′-bis­[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine. The copper centre assumes a tetra­gonally distorted pseudo-octa­hedral geometry with the O atoms of two trifluoro­methane­sulfonate anions coordinated weakly in the axial positions. The Cu—N distances lie in the range 1.941 (3)–2.011 (3) Å and the Cu—O distances are 2.474 (3) and 2.564 (3) Å.

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