{N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(trifluoro­methane­sulfanato-κO)copper(II)

A discrete neutral Cu(II) complex, [Cu(CF(3)SO(3))(2)(C(16)H(18)N(4))], has been derived from the symmetrical tetra­dentate Schiff base, N,N′-bis­[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine. The copper centre assumes a tetra­gonally distorted pseudo-octa­hedral geometry with the O atoms of two t...

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Detalles Bibliográficos
Autores principales: Coles, Simon J., Sengul, Abdurrahman, Kurt, Ozgur, Altin, Safinaz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959593/
https://www.ncbi.nlm.nih.gov/pubmed/21580878
http://dx.doi.org/10.1107/S1600536808033151
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author Coles, Simon J.
Sengul, Abdurrahman
Kurt, Ozgur
Altin, Safinaz
author_facet Coles, Simon J.
Sengul, Abdurrahman
Kurt, Ozgur
Altin, Safinaz
author_sort Coles, Simon J.
collection PubMed
description A discrete neutral Cu(II) complex, [Cu(CF(3)SO(3))(2)(C(16)H(18)N(4))], has been derived from the symmetrical tetra­dentate Schiff base, N,N′-bis­[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine. The copper centre assumes a tetra­gonally distorted pseudo-octa­hedral geometry with the O atoms of two trifluoro­methane­sulfonate anions coordinated weakly in the axial positions. The Cu—N distances lie in the range 1.941 (3)–2.011 (3) Å and the Cu—O distances are 2.474 (3) and 2.564 (3) Å.
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spelling pubmed-29595932010-12-30 {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(trifluoro­methane­sulfanato-κO)copper(II) Coles, Simon J. Sengul, Abdurrahman Kurt, Ozgur Altin, Safinaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers A discrete neutral Cu(II) complex, [Cu(CF(3)SO(3))(2)(C(16)H(18)N(4))], has been derived from the symmetrical tetra­dentate Schiff base, N,N′-bis­[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine. The copper centre assumes a tetra­gonally distorted pseudo-octa­hedral geometry with the O atoms of two trifluoro­methane­sulfonate anions coordinated weakly in the axial positions. The Cu—N distances lie in the range 1.941 (3)–2.011 (3) Å and the Cu—O distances are 2.474 (3) and 2.564 (3) Å. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959593/ /pubmed/21580878 http://dx.doi.org/10.1107/S1600536808033151 Text en © Coles et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Coles, Simon J.
Sengul, Abdurrahman
Kurt, Ozgur
Altin, Safinaz
{N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(trifluoro­methane­sulfanato-κO)copper(II)
title {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(trifluoro­methane­sulfanato-κO)copper(II)
title_full {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(trifluoro­methane­sulfanato-κO)copper(II)
title_fullStr {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(trifluoro­methane­sulfanato-κO)copper(II)
title_full_unstemmed {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(trifluoro­methane­sulfanato-κO)copper(II)
title_short {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(trifluoro­methane­sulfanato-κO)copper(II)
title_sort {n,n′-bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) n,n′,n′′,n′′′}bis­(trifluoro­methane­sulfanato-κo)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959593/
https://www.ncbi.nlm.nih.gov/pubmed/21580878
http://dx.doi.org/10.1107/S1600536808033151
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