Bis[2-hydr­oxy-N′-(2-hydroxy­benzo­yl)benzohydrazitato]dipyridine­cadmium(II)

The title complex, [Cd(C(14)H(11)N(2)O(4))(2)(C(5)H(5)N)(2)], exhibits crystallographic twofold symmetry. The Cd(II) atom is located on the twofold rotation axis and reveals a slightly distorted octa­hedral coordination defined by four atoms (N(2)O(2)) from two symmetry-related chelate ligands and t...

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Detalles Bibliográficos
Autores principales: Chen, Yu-Ting, Li, Da-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959594/
https://www.ncbi.nlm.nih.gov/pubmed/21580903
http://dx.doi.org/10.1107/S1600536808034533
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author Chen, Yu-Ting
Li, Da-Cheng
author_facet Chen, Yu-Ting
Li, Da-Cheng
author_sort Chen, Yu-Ting
collection PubMed
description The title complex, [Cd(C(14)H(11)N(2)O(4))(2)(C(5)H(5)N)(2)], exhibits crystallographic twofold symmetry. The Cd(II) atom is located on the twofold rotation axis and reveals a slightly distorted octa­hedral coordination defined by four atoms (N(2)O(2)) from two symmetry-related chelate ligands and two pyridine N atoms. Intra­molecular O—H⋯O and N—H⋯O hydrogen bonds stabilize the mol­ecular conformation while inter­molecular O—H⋯O hydrogen bonding links mol­ecules into a triad, generating a helix along the threefold screw axis.
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spelling pubmed-29595942010-12-30 Bis[2-hydr­oxy-N′-(2-hydroxy­benzo­yl)benzohydrazitato]dipyridine­cadmium(II) Chen, Yu-Ting Li, Da-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cd(C(14)H(11)N(2)O(4))(2)(C(5)H(5)N)(2)], exhibits crystallographic twofold symmetry. The Cd(II) atom is located on the twofold rotation axis and reveals a slightly distorted octa­hedral coordination defined by four atoms (N(2)O(2)) from two symmetry-related chelate ligands and two pyridine N atoms. Intra­molecular O—H⋯O and N—H⋯O hydrogen bonds stabilize the mol­ecular conformation while inter­molecular O—H⋯O hydrogen bonding links mol­ecules into a triad, generating a helix along the threefold screw axis. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959594/ /pubmed/21580903 http://dx.doi.org/10.1107/S1600536808034533 Text en © Chen and Li 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Yu-Ting
Li, Da-Cheng
Bis[2-hydr­oxy-N′-(2-hydroxy­benzo­yl)benzohydrazitato]dipyridine­cadmium(II)
title Bis[2-hydr­oxy-N′-(2-hydroxy­benzo­yl)benzohydrazitato]dipyridine­cadmium(II)
title_full Bis[2-hydr­oxy-N′-(2-hydroxy­benzo­yl)benzohydrazitato]dipyridine­cadmium(II)
title_fullStr Bis[2-hydr­oxy-N′-(2-hydroxy­benzo­yl)benzohydrazitato]dipyridine­cadmium(II)
title_full_unstemmed Bis[2-hydr­oxy-N′-(2-hydroxy­benzo­yl)benzohydrazitato]dipyridine­cadmium(II)
title_short Bis[2-hydr­oxy-N′-(2-hydroxy­benzo­yl)benzohydrazitato]dipyridine­cadmium(II)
title_sort bis[2-hydr­oxy-n′-(2-hydroxy­benzo­yl)benzohydrazitato]dipyridine­cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959594/
https://www.ncbi.nlm.nih.gov/pubmed/21580903
http://dx.doi.org/10.1107/S1600536808034533
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AT lidacheng bis2hydroxyn2hydroxybenzoylbenzohydrazitatodipyridinecadmiumii

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