(E)-N′-[2-(4-Chloro-3-nitro­phenyl­sulfon­yloxy)-3-methoxy­benzyl­idene]isonicotinohydrazide acetic acid tetra­solvate

In the title compound, C(20)H(15)ClN(4)O(7)S·4CH(3)COOH, the central o-vanillin group makes dihedral angles of 9.50 (11) and 42.86 (7)°, respectively, with its attached pyridine and nitro­benzene rings. The crystal packing is stabilized by N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds and C—H⋯O inter­action...

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Detalles Bibliográficos
Autores principales: Zhen, Xiao-Li, Li, Xiao-Liu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959596/
https://www.ncbi.nlm.nih.gov/pubmed/21581030
http://dx.doi.org/10.1107/S1600536808034089
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author Zhen, Xiao-Li
Li, Xiao-Liu
author_facet Zhen, Xiao-Li
Li, Xiao-Liu
author_sort Zhen, Xiao-Li
collection PubMed
description In the title compound, C(20)H(15)ClN(4)O(7)S·4CH(3)COOH, the central o-vanillin group makes dihedral angles of 9.50 (11) and 42.86 (7)°, respectively, with its attached pyridine and nitro­benzene rings. The crystal packing is stabilized by N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds and C—H⋯O inter­actions, leading to an infinite three-dimensional network. A short intramolecular C—H⋯O contact is also seen.
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spelling pubmed-29595962010-12-30 (E)-N′-[2-(4-Chloro-3-nitro­phenyl­sulfon­yloxy)-3-methoxy­benzyl­idene]isonicotinohydrazide acetic acid tetra­solvate Zhen, Xiao-Li Li, Xiao-Liu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(15)ClN(4)O(7)S·4CH(3)COOH, the central o-vanillin group makes dihedral angles of 9.50 (11) and 42.86 (7)°, respectively, with its attached pyridine and nitro­benzene rings. The crystal packing is stabilized by N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds and C—H⋯O inter­actions, leading to an infinite three-dimensional network. A short intramolecular C—H⋯O contact is also seen. International Union of Crystallography 2008-10-22 /pmc/articles/PMC2959596/ /pubmed/21581030 http://dx.doi.org/10.1107/S1600536808034089 Text en © Zhen and Li 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhen, Xiao-Li
Li, Xiao-Liu
(E)-N′-[2-(4-Chloro-3-nitro­phenyl­sulfon­yloxy)-3-methoxy­benzyl­idene]isonicotinohydrazide acetic acid tetra­solvate
title (E)-N′-[2-(4-Chloro-3-nitro­phenyl­sulfon­yloxy)-3-methoxy­benzyl­idene]isonicotinohydrazide acetic acid tetra­solvate
title_full (E)-N′-[2-(4-Chloro-3-nitro­phenyl­sulfon­yloxy)-3-methoxy­benzyl­idene]isonicotinohydrazide acetic acid tetra­solvate
title_fullStr (E)-N′-[2-(4-Chloro-3-nitro­phenyl­sulfon­yloxy)-3-methoxy­benzyl­idene]isonicotinohydrazide acetic acid tetra­solvate
title_full_unstemmed (E)-N′-[2-(4-Chloro-3-nitro­phenyl­sulfon­yloxy)-3-methoxy­benzyl­idene]isonicotinohydrazide acetic acid tetra­solvate
title_short (E)-N′-[2-(4-Chloro-3-nitro­phenyl­sulfon­yloxy)-3-methoxy­benzyl­idene]isonicotinohydrazide acetic acid tetra­solvate
title_sort (e)-n′-[2-(4-chloro-3-nitro­phenyl­sulfon­yloxy)-3-methoxy­benzyl­idene]isonicotinohydrazide acetic acid tetra­solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959596/
https://www.ncbi.nlm.nih.gov/pubmed/21581030
http://dx.doi.org/10.1107/S1600536808034089
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AT lixiaoliu en24chloro3nitrophenylsulfonyloxy3methoxybenzylideneisonicotinohydrazideaceticacidtetrasolvate

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