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(2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxybenzoato-κ(2) O,O′)(nitrato-κO)copper(II)
In the title compound, [Cu(C(7)H(5)O(3))(NO(3))(C(14)H(12)N(2))], the Cu(II) ion is five-coordinated in a slightly distorted square-pyramidal geometry by one O atom of a nitrate anion, two O atoms of a 4-hydroxybenzoate anion, and two N atoms from a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphe...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959601/ https://www.ncbi.nlm.nih.gov/pubmed/21580912 http://dx.doi.org/10.1107/S1600536808034788 |
Sumario: | In the title compound, [Cu(C(7)H(5)O(3))(NO(3))(C(14)H(12)N(2))], the Cu(II) ion is five-coordinated in a slightly distorted square-pyramidal geometry by one O atom of a nitrate anion, two O atoms of a 4-hydroxybenzoate anion, and two N atoms from a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand. In the crystal structure, inversion-related molecules are linked into dimers by O—H⋯O hydrogen bonds. The packing is further stabilized by π–π interactions involving the benzene rings of the dmphen and hydroxybenzoate units, with centroid–centroid distances of 3.4930 (14) or 3.5727 (14) Å. |
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