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(2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxybenzoato-κ(2) O,O′)(nitrato-κO)copper(II)
In the title compound, [Cu(C(7)H(5)O(3))(NO(3))(C(14)H(12)N(2))], the Cu(II) ion is five-coordinated in a slightly distorted square-pyramidal geometry by one O atom of a nitrate anion, two O atoms of a 4-hydroxybenzoate anion, and two N atoms from a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphe...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959601/ https://www.ncbi.nlm.nih.gov/pubmed/21580912 http://dx.doi.org/10.1107/S1600536808034788 |
| _version_ | 1782188538699186176 |
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| author | Zhai, Cui-Ping Yan, Feng-Mei Zhao, Pei-Zheng |
| author_facet | Zhai, Cui-Ping Yan, Feng-Mei Zhao, Pei-Zheng |
| author_sort | Zhai, Cui-Ping |
| collection | PubMed |
| description | In the title compound, [Cu(C(7)H(5)O(3))(NO(3))(C(14)H(12)N(2))], the Cu(II) ion is five-coordinated in a slightly distorted square-pyramidal geometry by one O atom of a nitrate anion, two O atoms of a 4-hydroxybenzoate anion, and two N atoms from a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand. In the crystal structure, inversion-related molecules are linked into dimers by O—H⋯O hydrogen bonds. The packing is further stabilized by π–π interactions involving the benzene rings of the dmphen and hydroxybenzoate units, with centroid–centroid distances of 3.4930 (14) or 3.5727 (14) Å. |
| format | Text |
| id | pubmed-2959601 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29596012010-12-30 (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxybenzoato-κ(2) O,O′)(nitrato-κO)copper(II) Zhai, Cui-Ping Yan, Feng-Mei Zhao, Pei-Zheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(7)H(5)O(3))(NO(3))(C(14)H(12)N(2))], the Cu(II) ion is five-coordinated in a slightly distorted square-pyramidal geometry by one O atom of a nitrate anion, two O atoms of a 4-hydroxybenzoate anion, and two N atoms from a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand. In the crystal structure, inversion-related molecules are linked into dimers by O—H⋯O hydrogen bonds. The packing is further stabilized by π–π interactions involving the benzene rings of the dmphen and hydroxybenzoate units, with centroid–centroid distances of 3.4930 (14) or 3.5727 (14) Å. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959601/ /pubmed/21580912 http://dx.doi.org/10.1107/S1600536808034788 Text en © Zhai et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhai, Cui-Ping Yan, Feng-Mei Zhao, Pei-Zheng (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxybenzoato-κ(2) O,O′)(nitrato-κO)copper(II) |
| title | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)(4-hydroxybenzoato-κ(2)
O,O′)(nitrato-κO)copper(II) |
| title_full | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)(4-hydroxybenzoato-κ(2)
O,O′)(nitrato-κO)copper(II) |
| title_fullStr | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)(4-hydroxybenzoato-κ(2)
O,O′)(nitrato-κO)copper(II) |
| title_full_unstemmed | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)(4-hydroxybenzoato-κ(2)
O,O′)(nitrato-κO)copper(II) |
| title_short | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)(4-hydroxybenzoato-κ(2)
O,O′)(nitrato-κO)copper(II) |
| title_sort | (2,9-dimethyl-1,10-phenanthroline-κ(2)
n,n′)(4-hydroxybenzoato-κ(2)
o,o′)(nitrato-κo)copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959601/ https://www.ncbi.nlm.nih.gov/pubmed/21580912 http://dx.doi.org/10.1107/S1600536808034788 |
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