1-(2,6-Difluoro­benzo­yl)-3-(2,3,5-tri­chloro­phen­yl)urea

The asymmetric unit of the title compound, C(14)H(7)Cl(3)F(2)N(2)O(2), contains two unique molecules. The 2,3,5-trichloro­phenyl ring is almost coplanar with the urea group in both molecules, whereas the 2,6-difluoro­phenyl ring is twisted from the urea plane by 54.83 (10)° in one molecule and 60.58...

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Detalles Bibliográficos
Autores principales: Yan, Sheng-Jiao, Huang, Chao, Li, Yan-Mei, Yan, Yu-Yun, Lin, Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959602/
https://www.ncbi.nlm.nih.gov/pubmed/21580966
http://dx.doi.org/10.1107/S1600536808032029
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author Yan, Sheng-Jiao
Huang, Chao
Li, Yan-Mei
Yan, Yu-Yun
Lin, Jun
author_facet Yan, Sheng-Jiao
Huang, Chao
Li, Yan-Mei
Yan, Yu-Yun
Lin, Jun
author_sort Yan, Sheng-Jiao
collection PubMed
description The asymmetric unit of the title compound, C(14)H(7)Cl(3)F(2)N(2)O(2), contains two unique molecules. The 2,3,5-trichloro­phenyl ring is almost coplanar with the urea group in both molecules, whereas the 2,6-difluoro­phenyl ring is twisted from the urea plane by 54.83 (10)° in one molecule and 60.58 (10)° in the other. An intra­molecular N—H—O hydrogen bond stabilizes the mol­ecular conformation. The crystal packing is formed by inter­molecular N—H—O hydrogen bonds and F⋯F inter­actions [2.841 (2) Å].
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spelling pubmed-29596022010-12-30 1-(2,6-Difluoro­benzo­yl)-3-(2,3,5-tri­chloro­phen­yl)urea Yan, Sheng-Jiao Huang, Chao Li, Yan-Mei Yan, Yu-Yun Lin, Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(14)H(7)Cl(3)F(2)N(2)O(2), contains two unique molecules. The 2,3,5-trichloro­phenyl ring is almost coplanar with the urea group in both molecules, whereas the 2,6-difluoro­phenyl ring is twisted from the urea plane by 54.83 (10)° in one molecule and 60.58 (10)° in the other. An intra­molecular N—H—O hydrogen bond stabilizes the mol­ecular conformation. The crystal packing is formed by inter­molecular N—H—O hydrogen bonds and F⋯F inter­actions [2.841 (2) Å]. International Union of Crystallography 2008-10-11 /pmc/articles/PMC2959602/ /pubmed/21580966 http://dx.doi.org/10.1107/S1600536808032029 Text en © Yan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yan, Sheng-Jiao
Huang, Chao
Li, Yan-Mei
Yan, Yu-Yun
Lin, Jun
1-(2,6-Difluoro­benzo­yl)-3-(2,3,5-tri­chloro­phen­yl)urea
title 1-(2,6-Difluoro­benzo­yl)-3-(2,3,5-tri­chloro­phen­yl)urea
title_full 1-(2,6-Difluoro­benzo­yl)-3-(2,3,5-tri­chloro­phen­yl)urea
title_fullStr 1-(2,6-Difluoro­benzo­yl)-3-(2,3,5-tri­chloro­phen­yl)urea
title_full_unstemmed 1-(2,6-Difluoro­benzo­yl)-3-(2,3,5-tri­chloro­phen­yl)urea
title_short 1-(2,6-Difluoro­benzo­yl)-3-(2,3,5-tri­chloro­phen­yl)urea
title_sort 1-(2,6-difluoro­benzo­yl)-3-(2,3,5-tri­chloro­phen­yl)urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959602/
https://www.ncbi.nlm.nih.gov/pubmed/21580966
http://dx.doi.org/10.1107/S1600536808032029
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AT liyanmei 126difluorobenzoyl3235trichlorophenylurea
AT yanyuyun 126difluorobenzoyl3235trichlorophenylurea
AT linjun 126difluorobenzoyl3235trichlorophenylurea

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