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trans-Dichloridobis(2,2-dimethylpropane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate
In the title salt, [CrCl(2)(C(5)H(14)N(2))(2)]ClO(4), the Cr atom is in a trans-CrCl(2)N(4) octahedral environment comprising the four N atoms of two chelating 2,2-dimethylpropane-1,3-diamine ligands and two Cl atoms. The two six-membered CrC(3)N(2) rings in the cation adopt anti chair–chair confo...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959603/ https://www.ncbi.nlm.nih.gov/pubmed/21580872 http://dx.doi.org/10.1107/S1600536808032911 |
Sumario: | In the title salt, [CrCl(2)(C(5)H(14)N(2))(2)]ClO(4), the Cr atom is in a trans-CrCl(2)N(4) octahedral environment comprising the four N atoms of two chelating 2,2-dimethylpropane-1,3-diamine ligands and two Cl atoms. The two six-membered CrC(3)N(2) rings in the cation adopt anti chair–chair conformations with respect to each other. The perchlorate anion is disordered over two positions in respect of the Cl and an O atom in a 6:4 ratio. N—H⋯O hydrogen bonds link the cations and anions into a layer structure. |
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