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trans-Dichloridobis(2,2-dimethyl­prop­ane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate

In the title salt, [CrCl(2)(C(5)H(14)N(2))(2)]ClO(4), the Cr atom is in a trans-CrCl(2)N(4) octa­hedral environment comprising the four N atoms of two chelating 2,2-dimethyl­propane-1,3-diamine ligands and two Cl atoms. The two six-membered CrC(3)N(2) rings in the cation adopt anti chair–chair confo...

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Detalles Bibliográficos
Autores principales: Choi, Jong-Ha, Lee, Sang Hak, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959603/
https://www.ncbi.nlm.nih.gov/pubmed/21580872
http://dx.doi.org/10.1107/S1600536808032911
Descripción
Sumario:In the title salt, [CrCl(2)(C(5)H(14)N(2))(2)]ClO(4), the Cr atom is in a trans-CrCl(2)N(4) octa­hedral environment comprising the four N atoms of two chelating 2,2-dimethyl­propane-1,3-diamine ligands and two Cl atoms. The two six-membered CrC(3)N(2) rings in the cation adopt anti chair–chair conformations with respect to each other. The perchlorate anion is disordered over two positions in respect of the Cl and an O atom in a 6:4 ratio. N—H⋯O hydrogen bonds link the cations and anions into a layer structure.