trans-Dichloridobis(2,2-dimethyl­prop­ane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate

In the title salt, [CrCl(2)(C(5)H(14)N(2))(2)]ClO(4), the Cr atom is in a trans-CrCl(2)N(4) octa­hedral environment comprising the four N atoms of two chelating 2,2-dimethyl­propane-1,3-diamine ligands and two Cl atoms. The two six-membered CrC(3)N(2) rings in the cation adopt anti chair–chair confo...

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Detalles Bibliográficos
Autores principales: Choi, Jong-Ha, Lee, Sang Hak, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959603/
https://www.ncbi.nlm.nih.gov/pubmed/21580872
http://dx.doi.org/10.1107/S1600536808032911
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author Choi, Jong-Ha
Lee, Sang Hak
Lee, Uk
author_facet Choi, Jong-Ha
Lee, Sang Hak
Lee, Uk
author_sort Choi, Jong-Ha
collection PubMed
description In the title salt, [CrCl(2)(C(5)H(14)N(2))(2)]ClO(4), the Cr atom is in a trans-CrCl(2)N(4) octa­hedral environment comprising the four N atoms of two chelating 2,2-dimethyl­propane-1,3-diamine ligands and two Cl atoms. The two six-membered CrC(3)N(2) rings in the cation adopt anti chair–chair conformations with respect to each other. The perchlorate anion is disordered over two positions in respect of the Cl and an O atom in a 6:4 ratio. N—H⋯O hydrogen bonds link the cations and anions into a layer structure.
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spelling pubmed-29596032010-12-30 trans-Dichloridobis(2,2-dimethyl­prop­ane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate Choi, Jong-Ha Lee, Sang Hak Lee, Uk Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [CrCl(2)(C(5)H(14)N(2))(2)]ClO(4), the Cr atom is in a trans-CrCl(2)N(4) octa­hedral environment comprising the four N atoms of two chelating 2,2-dimethyl­propane-1,3-diamine ligands and two Cl atoms. The two six-membered CrC(3)N(2) rings in the cation adopt anti chair–chair conformations with respect to each other. The perchlorate anion is disordered over two positions in respect of the Cl and an O atom in a 6:4 ratio. N—H⋯O hydrogen bonds link the cations and anions into a layer structure. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959603/ /pubmed/21580872 http://dx.doi.org/10.1107/S1600536808032911 Text en © Choi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Choi, Jong-Ha
Lee, Sang Hak
Lee, Uk
trans-Dichloridobis(2,2-dimethyl­prop­ane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate
title trans-Dichloridobis(2,2-dimethyl­prop­ane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate
title_full trans-Dichloridobis(2,2-dimethyl­prop­ane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate
title_fullStr trans-Dichloridobis(2,2-dimethyl­prop­ane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate
title_full_unstemmed trans-Dichloridobis(2,2-dimethyl­prop­ane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate
title_short trans-Dichloridobis(2,2-dimethyl­prop­ane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate
title_sort trans-dichloridobis(2,2-dimethyl­prop­ane-1,3-diamine-κ(2) n,n′)chromium(iii) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959603/
https://www.ncbi.nlm.nih.gov/pubmed/21580872
http://dx.doi.org/10.1107/S1600536808032911
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