(O,O′-Diethyl dithio­phosphato-κ(2) S,S′)(hydridotripyrazol-1-ylborato-κ(3) N (2),N (2′),N (2′′))(triphenyl­phosphine-κP)ruthenium(II)

Reaction of [Ru(Tp)Cl(PPh(3))(2)] {where Tp is hydridotri­pyrazol­yl­borate, BH[C(3)H(3)N(2))(3))]} with NH(4)[S(2)P(OEt)(2)] in methanol afforded the title compound, [Ru(C(9)H(10)BN(6))(C(4)H(10)O(2)PS(2))(C(18)H(15)P)], in which the Ru(II) ion is in a slightly disorted octa­hedral coordination env...

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Autores principales: Tong, Hung-Chun, Chen Hsu, Chih-Yung, Liang, Yao-Ren, Lo, Yih Hsing, Lin, Chia-Her
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959604/
https://www.ncbi.nlm.nih.gov/pubmed/21580829
http://dx.doi.org/10.1107/S160053680803170X
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author Tong, Hung-Chun
Chen Hsu, Chih-Yung
Liang, Yao-Ren
Lo, Yih Hsing
Lin, Chia-Her
author_facet Tong, Hung-Chun
Chen Hsu, Chih-Yung
Liang, Yao-Ren
Lo, Yih Hsing
Lin, Chia-Her
author_sort Tong, Hung-Chun
collection PubMed
description Reaction of [Ru(Tp)Cl(PPh(3))(2)] {where Tp is hydridotri­pyrazol­yl­borate, BH[C(3)H(3)N(2))(3))]} with NH(4)[S(2)P(OEt)(2)] in methanol afforded the title compound, [Ru(C(9)H(10)BN(6))(C(4)H(10)O(2)PS(2))(C(18)H(15)P)], in which the Ru(II) ion is in a slightly disorted octa­hedral coordination environment. The [S(2)P(OEt)(2)](−) ligand coordinates in a chelating mode with two similar Ru—S bond lengths and a slightly acute S—Ru—S angle. The atoms of both –OCH(2)CH(3) groups of the diethyl dithio­phosphate ligand are disordered over two sites with approximate occupancies of 0.76 and 0.24.
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spelling pubmed-29596042010-12-30 (O,O′-Diethyl dithio­phosphato-κ(2) S,S′)(hydridotripyrazol-1-ylborato-κ(3) N (2),N (2′),N (2′′))(triphenyl­phosphine-κP)ruthenium(II) Tong, Hung-Chun Chen Hsu, Chih-Yung Liang, Yao-Ren Lo, Yih Hsing Lin, Chia-Her Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Reaction of [Ru(Tp)Cl(PPh(3))(2)] {where Tp is hydridotri­pyrazol­yl­borate, BH[C(3)H(3)N(2))(3))]} with NH(4)[S(2)P(OEt)(2)] in methanol afforded the title compound, [Ru(C(9)H(10)BN(6))(C(4)H(10)O(2)PS(2))(C(18)H(15)P)], in which the Ru(II) ion is in a slightly disorted octa­hedral coordination environment. The [S(2)P(OEt)(2)](−) ligand coordinates in a chelating mode with two similar Ru—S bond lengths and a slightly acute S—Ru—S angle. The atoms of both –OCH(2)CH(3) groups of the diethyl dithio­phosphate ligand are disordered over two sites with approximate occupancies of 0.76 and 0.24. International Union of Crystallography 2008-10-09 /pmc/articles/PMC2959604/ /pubmed/21580829 http://dx.doi.org/10.1107/S160053680803170X Text en © Tong et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tong, Hung-Chun
Chen Hsu, Chih-Yung
Liang, Yao-Ren
Lo, Yih Hsing
Lin, Chia-Her
(O,O′-Diethyl dithio­phosphato-κ(2) S,S′)(hydridotripyrazol-1-ylborato-κ(3) N (2),N (2′),N (2′′))(triphenyl­phosphine-κP)ruthenium(II)
title (O,O′-Diethyl dithio­phosphato-κ(2) S,S′)(hydridotripyrazol-1-ylborato-κ(3) N (2),N (2′),N (2′′))(triphenyl­phosphine-κP)ruthenium(II)
title_full (O,O′-Diethyl dithio­phosphato-κ(2) S,S′)(hydridotripyrazol-1-ylborato-κ(3) N (2),N (2′),N (2′′))(triphenyl­phosphine-κP)ruthenium(II)
title_fullStr (O,O′-Diethyl dithio­phosphato-κ(2) S,S′)(hydridotripyrazol-1-ylborato-κ(3) N (2),N (2′),N (2′′))(triphenyl­phosphine-κP)ruthenium(II)
title_full_unstemmed (O,O′-Diethyl dithio­phosphato-κ(2) S,S′)(hydridotripyrazol-1-ylborato-κ(3) N (2),N (2′),N (2′′))(triphenyl­phosphine-κP)ruthenium(II)
title_short (O,O′-Diethyl dithio­phosphato-κ(2) S,S′)(hydridotripyrazol-1-ylborato-κ(3) N (2),N (2′),N (2′′))(triphenyl­phosphine-κP)ruthenium(II)
title_sort (o,o′-diethyl dithio­phosphato-κ(2) s,s′)(hydridotripyrazol-1-ylborato-κ(3) n (2),n (2′),n (2′′))(triphenyl­phosphine-κp)ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959604/
https://www.ncbi.nlm.nih.gov/pubmed/21580829
http://dx.doi.org/10.1107/S160053680803170X
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