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catena-Poly[[[aqua(pyridine-2,6-dicarboxylato N-oxide-κ(2) O (1),O (2))cobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′] dihydrate]
In the title compound, {[Co(C(7)H(3)NO(5))(C(13)H(14)N(2))(H(2)O)]·2H(2)O}(n), the Co(II) atom is coordinated by two O atoms from a pyridine-2,6-dicarboxylate N-oxide ligand, two N atoms from two 1,3-di-4-pyridylpropane ligands and one water molecule, and displays a distorted square-pyramidal coor...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959606/ https://www.ncbi.nlm.nih.gov/pubmed/21580863 http://dx.doi.org/10.1107/S1600536808032741 |
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author | Wang, Li-Jin |
author_facet | Wang, Li-Jin |
author_sort | Wang, Li-Jin |
collection | PubMed |
description | In the title compound, {[Co(C(7)H(3)NO(5))(C(13)H(14)N(2))(H(2)O)]·2H(2)O}(n), the Co(II) atom is coordinated by two O atoms from a pyridine-2,6-dicarboxylate N-oxide ligand, two N atoms from two 1,3-di-4-pyridylpropane ligands and one water molecule, and displays a distorted square-pyramidal coordination geometry. The 1,3-di-4-pyridylpropane ligands link the Co(II) atoms into an infinite zigzag chain parallel to [010]. The chains are further linked through O—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional supramolecular network. |
format | Text |
id | pubmed-2959606 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29596062010-12-30 catena-Poly[[[aqua(pyridine-2,6-dicarboxylato N-oxide-κ(2) O (1),O (2))cobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′] dihydrate] Wang, Li-Jin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Co(C(7)H(3)NO(5))(C(13)H(14)N(2))(H(2)O)]·2H(2)O}(n), the Co(II) atom is coordinated by two O atoms from a pyridine-2,6-dicarboxylate N-oxide ligand, two N atoms from two 1,3-di-4-pyridylpropane ligands and one water molecule, and displays a distorted square-pyramidal coordination geometry. The 1,3-di-4-pyridylpropane ligands link the Co(II) atoms into an infinite zigzag chain parallel to [010]. The chains are further linked through O—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional supramolecular network. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959606/ /pubmed/21580863 http://dx.doi.org/10.1107/S1600536808032741 Text en © Li-Jin Wang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Li-Jin catena-Poly[[[aqua(pyridine-2,6-dicarboxylato N-oxide-κ(2) O (1),O (2))cobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′] dihydrate] |
title |
catena-Poly[[[aqua(pyridine-2,6-dicarboxylato N-oxide-κ(2)
O
(1),O
(2))cobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2)
N:N′] dihydrate] |
title_full |
catena-Poly[[[aqua(pyridine-2,6-dicarboxylato N-oxide-κ(2)
O
(1),O
(2))cobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2)
N:N′] dihydrate] |
title_fullStr |
catena-Poly[[[aqua(pyridine-2,6-dicarboxylato N-oxide-κ(2)
O
(1),O
(2))cobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2)
N:N′] dihydrate] |
title_full_unstemmed |
catena-Poly[[[aqua(pyridine-2,6-dicarboxylato N-oxide-κ(2)
O
(1),O
(2))cobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2)
N:N′] dihydrate] |
title_short |
catena-Poly[[[aqua(pyridine-2,6-dicarboxylato N-oxide-κ(2)
O
(1),O
(2))cobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2)
N:N′] dihydrate] |
title_sort | catena-poly[[[aqua(pyridine-2,6-dicarboxylato n-oxide-κ(2)
o
(1),o
(2))cobalt(ii)]-μ-1,3-di-4-pyridylpropane-κ(2)
n:n′] dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959606/ https://www.ncbi.nlm.nih.gov/pubmed/21580863 http://dx.doi.org/10.1107/S1600536808032741 |
work_keys_str_mv | AT wanglijin catenapolyaquapyridine26dicarboxylatonoxidek2o1o2cobaltiim13di4pyridylpropanek2nndihydrate |