1,3-Dimesitylimidazolidinium tetra­chloridogold(III) dichloro­methane solvate

The title ionic compound, (C(21)H(27)N(2))[AuCl(4)]·CH(2)Cl(2), was obtained from the reaction of 1,3-dimesitylimidazolidinium chloride with t-BuOK and a solution of AuCl(3) in tetra­hydro­furan. In the crystal structure, numerous weak C—H⋯Cl hydrogen bonds form double layers parallel to (100), whic...

Descripción completa

Detalles Bibliográficos
Autores principales: Hagos, Tesfamariam K., Nogai, Stefan D., Dobrzańska, Liliana, Cronje, Stephanie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959617/
https://www.ncbi.nlm.nih.gov/pubmed/21580818
http://dx.doi.org/10.1107/S1600536808031115
_version_ 1782188542653366272
author Hagos, Tesfamariam K.
Nogai, Stefan D.
Dobrzańska, Liliana
Cronje, Stephanie
author_facet Hagos, Tesfamariam K.
Nogai, Stefan D.
Dobrzańska, Liliana
Cronje, Stephanie
author_sort Hagos, Tesfamariam K.
collection PubMed
description The title ionic compound, (C(21)H(27)N(2))[AuCl(4)]·CH(2)Cl(2), was obtained from the reaction of 1,3-dimesitylimidazolidinium chloride with t-BuOK and a solution of AuCl(3) in tetra­hydro­furan. In the crystal structure, numerous weak C—H⋯Cl hydrogen bonds form double layers parallel to (100), which are further stabilized by π–π inter­actions between mesitylene rings [centroid–centroid distance = 4.308 (4) Å], resulting in the formation of a three-dimensional supra­molecular assembly.
format Text
id pubmed-2959617
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29596172010-12-30 1,3-Dimesitylimidazolidinium tetra­chloridogold(III) dichloro­methane solvate Hagos, Tesfamariam K. Nogai, Stefan D. Dobrzańska, Liliana Cronje, Stephanie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title ionic compound, (C(21)H(27)N(2))[AuCl(4)]·CH(2)Cl(2), was obtained from the reaction of 1,3-dimesitylimidazolidinium chloride with t-BuOK and a solution of AuCl(3) in tetra­hydro­furan. In the crystal structure, numerous weak C—H⋯Cl hydrogen bonds form double layers parallel to (100), which are further stabilized by π–π inter­actions between mesitylene rings [centroid–centroid distance = 4.308 (4) Å], resulting in the formation of a three-dimensional supra­molecular assembly. International Union of Crystallography 2008-10-04 /pmc/articles/PMC2959617/ /pubmed/21580818 http://dx.doi.org/10.1107/S1600536808031115 Text en © Hagos et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hagos, Tesfamariam K.
Nogai, Stefan D.
Dobrzańska, Liliana
Cronje, Stephanie
1,3-Dimesitylimidazolidinium tetra­chloridogold(III) dichloro­methane solvate
title 1,3-Dimesitylimidazolidinium tetra­chloridogold(III) dichloro­methane solvate
title_full 1,3-Dimesitylimidazolidinium tetra­chloridogold(III) dichloro­methane solvate
title_fullStr 1,3-Dimesitylimidazolidinium tetra­chloridogold(III) dichloro­methane solvate
title_full_unstemmed 1,3-Dimesitylimidazolidinium tetra­chloridogold(III) dichloro­methane solvate
title_short 1,3-Dimesitylimidazolidinium tetra­chloridogold(III) dichloro­methane solvate
title_sort 1,3-dimesitylimidazolidinium tetra­chloridogold(iii) dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959617/
https://www.ncbi.nlm.nih.gov/pubmed/21580818
http://dx.doi.org/10.1107/S1600536808031115
work_keys_str_mv AT hagostesfamariamk 13dimesitylimidazolidiniumtetrachloridogoldiiidichloromethanesolvate
AT nogaistefand 13dimesitylimidazolidiniumtetrachloridogoldiiidichloromethanesolvate
AT dobrzanskaliliana 13dimesitylimidazolidiniumtetrachloridogoldiiidichloromethanesolvate
AT cronjestephanie 13dimesitylimidazolidiniumtetrachloridogoldiiidichloromethanesolvate

Ejemplares similares