catena-Poly[[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]phenolato}­cad­mium(II)]-di-μ(2)-chlorido-[dimethanol­cadmium(II)]-di-μ(2)-chlorido-[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]­phenolato}cadmium(II)]-di-μ(2)-chlorido]

The structure of the title compound, [Cd(3)Cl(6)(C(15)H(15)NO(2))(2)(CH(4)O)(2)](n), is based on a layered zigzag polymeric chain along the c axis. The Cd(II) ions are linked by double chlorine bridges alternating between one CdCl(4)(CH(3)OH)(2) and two CdCl(4)(C(15)H(15)NO(2)) octa­hedral coordinat...

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Detalles Bibliográficos
Autores principales: Xian, Hui-Duo, Li, Hua-Qiong, Liu, Jian-Feng, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959620/
https://www.ncbi.nlm.nih.gov/pubmed/21580884
http://dx.doi.org/10.1107/S1600536808033527
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author Xian, Hui-Duo
Li, Hua-Qiong
Liu, Jian-Feng
Zhao, Guo-Liang
author_facet Xian, Hui-Duo
Li, Hua-Qiong
Liu, Jian-Feng
Zhao, Guo-Liang
author_sort Xian, Hui-Duo
collection PubMed
description The structure of the title compound, [Cd(3)Cl(6)(C(15)H(15)NO(2))(2)(CH(4)O)(2)](n), is based on a layered zigzag polymeric chain along the c axis. The Cd(II) ions are linked by double chlorine bridges alternating between one CdCl(4)(CH(3)OH)(2) and two CdCl(4)(C(15)H(15)NO(2)) octa­hedral coordination units. Additional intrachain N—H⋯O and O—H⋯Cl hydrogen-bond interactions stabilize this arrangement.
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spelling pubmed-29596202010-12-30 catena-Poly[[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]phenolato}­cad­mium(II)]-di-μ(2)-chlorido-[dimethanol­cadmium(II)]-di-μ(2)-chlorido-[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]­phenolato}cadmium(II)]-di-μ(2)-chlorido] Xian, Hui-Duo Li, Hua-Qiong Liu, Jian-Feng Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Cd(3)Cl(6)(C(15)H(15)NO(2))(2)(CH(4)O)(2)](n), is based on a layered zigzag polymeric chain along the c axis. The Cd(II) ions are linked by double chlorine bridges alternating between one CdCl(4)(CH(3)OH)(2) and two CdCl(4)(C(15)H(15)NO(2)) octa­hedral coordination units. Additional intrachain N—H⋯O and O—H⋯Cl hydrogen-bond interactions stabilize this arrangement. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959620/ /pubmed/21580884 http://dx.doi.org/10.1107/S1600536808033527 Text en © Xian et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xian, Hui-Duo
Li, Hua-Qiong
Liu, Jian-Feng
Zhao, Guo-Liang
catena-Poly[[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]phenolato}­cad­mium(II)]-di-μ(2)-chlorido-[dimethanol­cadmium(II)]-di-μ(2)-chlorido-[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]­phenolato}cadmium(II)]-di-μ(2)-chlorido]
title catena-Poly[[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]phenolato}­cad­mium(II)]-di-μ(2)-chlorido-[dimethanol­cadmium(II)]-di-μ(2)-chlorido-[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]­phenolato}cadmium(II)]-di-μ(2)-chlorido]
title_full catena-Poly[[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]phenolato}­cad­mium(II)]-di-μ(2)-chlorido-[dimethanol­cadmium(II)]-di-μ(2)-chlorido-[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]­phenolato}cadmium(II)]-di-μ(2)-chlorido]
title_fullStr catena-Poly[[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]phenolato}­cad­mium(II)]-di-μ(2)-chlorido-[dimethanol­cadmium(II)]-di-μ(2)-chlorido-[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]­phenolato}cadmium(II)]-di-μ(2)-chlorido]
title_full_unstemmed catena-Poly[[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]phenolato}­cad­mium(II)]-di-μ(2)-chlorido-[dimethanol­cadmium(II)]-di-μ(2)-chlorido-[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]­phenolato}cadmium(II)]-di-μ(2)-chlorido]
title_short catena-Poly[[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]phenolato}­cad­mium(II)]-di-μ(2)-chlorido-[dimethanol­cadmium(II)]-di-μ(2)-chlorido-[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]­phenolato}cadmium(II)]-di-μ(2)-chlorido]
title_sort catena-poly[[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]phenolato}­cad­mium(ii)]-di-μ(2)-chlorido-[dimethanol­cadmium(ii)]-di-μ(2)-chlorido-[{2-meth­oxy-6-[(4-methyl­phen­yl)imino­meth­yl]­phenolato}cadmium(ii)]-di-μ(2)-chlorido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959620/
https://www.ncbi.nlm.nih.gov/pubmed/21580884
http://dx.doi.org/10.1107/S1600536808033527
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