1-[6-(Hydroxy­meth­yl)-2-pyrid­yl]-3-(2,4,6-trimethyl­benz­yl)-1H-imidazol-3-ium bromide

In the title compound, C(19)H(22)N(3)O(+)·Br(−), the imidazole ring is approximately coplanar with the pyridine ring [dihedral angle = 0.88 (13)°] and nearly perpendicular to the benzene ring [dihedral angle = 81.70 (13)°]. O—H⋯Br and C—H⋯Br hydrogen bonding helps to stabilize the crystal structure....

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Detalles Bibliográficos
Autores principales: Zhou, Chuang, Zhou, Xiang-Ge, Qiu, Yu-Ping, Luo, Mei-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959624/
https://www.ncbi.nlm.nih.gov/pubmed/21581080
http://dx.doi.org/10.1107/S1600536808034764
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author Zhou, Chuang
Zhou, Xiang-Ge
Qiu, Yu-Ping
Luo, Mei-Ming
author_facet Zhou, Chuang
Zhou, Xiang-Ge
Qiu, Yu-Ping
Luo, Mei-Ming
author_sort Zhou, Chuang
collection PubMed
description In the title compound, C(19)H(22)N(3)O(+)·Br(−), the imidazole ring is approximately coplanar with the pyridine ring [dihedral angle = 0.88 (13)°] and nearly perpendicular to the benzene ring [dihedral angle = 81.70 (13)°]. O—H⋯Br and C—H⋯Br hydrogen bonding helps to stabilize the crystal structure.
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spelling pubmed-29596242010-12-30 1-[6-(Hydroxy­meth­yl)-2-pyrid­yl]-3-(2,4,6-trimethyl­benz­yl)-1H-imidazol-3-ium bromide Zhou, Chuang Zhou, Xiang-Ge Qiu, Yu-Ping Luo, Mei-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(22)N(3)O(+)·Br(−), the imidazole ring is approximately coplanar with the pyridine ring [dihedral angle = 0.88 (13)°] and nearly perpendicular to the benzene ring [dihedral angle = 81.70 (13)°]. O—H⋯Br and C—H⋯Br hydrogen bonding helps to stabilize the crystal structure. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959624/ /pubmed/21581080 http://dx.doi.org/10.1107/S1600536808034764 Text en © Zhou et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhou, Chuang
Zhou, Xiang-Ge
Qiu, Yu-Ping
Luo, Mei-Ming
1-[6-(Hydroxy­meth­yl)-2-pyrid­yl]-3-(2,4,6-trimethyl­benz­yl)-1H-imidazol-3-ium bromide
title 1-[6-(Hydroxy­meth­yl)-2-pyrid­yl]-3-(2,4,6-trimethyl­benz­yl)-1H-imidazol-3-ium bromide
title_full 1-[6-(Hydroxy­meth­yl)-2-pyrid­yl]-3-(2,4,6-trimethyl­benz­yl)-1H-imidazol-3-ium bromide
title_fullStr 1-[6-(Hydroxy­meth­yl)-2-pyrid­yl]-3-(2,4,6-trimethyl­benz­yl)-1H-imidazol-3-ium bromide
title_full_unstemmed 1-[6-(Hydroxy­meth­yl)-2-pyrid­yl]-3-(2,4,6-trimethyl­benz­yl)-1H-imidazol-3-ium bromide
title_short 1-[6-(Hydroxy­meth­yl)-2-pyrid­yl]-3-(2,4,6-trimethyl­benz­yl)-1H-imidazol-3-ium bromide
title_sort 1-[6-(hydroxy­meth­yl)-2-pyrid­yl]-3-(2,4,6-trimethyl­benz­yl)-1h-imidazol-3-ium bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959624/
https://www.ncbi.nlm.nih.gov/pubmed/21581080
http://dx.doi.org/10.1107/S1600536808034764
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AT qiuyuping 16hydroxymethyl2pyridyl3246trimethylbenzyl1himidazol3iumbromide
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