Dichlorido{μ-6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethyl­formamide solvate

In the heterodinuclear complex of the title compound, [PbZn(C(22)H(18)N(2)O(4))Cl(2)(C(2)H(6)OS)]·C(3)H(7)NO, the Zn(II) atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The Pb...

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Detalles Bibliográficos
Autores principales: Wang, Hailong, Zhang, Daopeng, Tian, Laijin, Zhang, Li-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959625/
https://www.ncbi.nlm.nih.gov/pubmed/21580898
http://dx.doi.org/10.1107/S1600536808034338
Descripción
Sumario:In the heterodinuclear complex of the title compound, [PbZn(C(22)H(18)N(2)O(4))Cl(2)(C(2)H(6)OS)]·C(3)H(7)NO, the Zn(II) atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The Pb(II) atom is coordinated in a distorted octa­hedral geometry by the four O atoms of the diphenolate ligand, one O atom from the dimethyl sulfoxide mol­ecule and one Cl atom. The dimethyl sulfoxide mol­ecule is disordered over two positions, with site occupancies of 0.576 (2) and 0.424 (2).

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