Dichlorido{μ-6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethyl­formamide solvate

In the heterodinuclear complex of the title compound, [PbZn(C(22)H(18)N(2)O(4))Cl(2)(C(2)H(6)OS)]·C(3)H(7)NO, the Zn(II) atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The Pb...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Hailong, Zhang, Daopeng, Tian, Laijin, Zhang, Li-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959625/
https://www.ncbi.nlm.nih.gov/pubmed/21580898
http://dx.doi.org/10.1107/S1600536808034338
_version_ 1782188544547094528
author Wang, Hailong
Zhang, Daopeng
Tian, Laijin
Zhang, Li-Fang
author_facet Wang, Hailong
Zhang, Daopeng
Tian, Laijin
Zhang, Li-Fang
author_sort Wang, Hailong
collection PubMed
description In the heterodinuclear complex of the title compound, [PbZn(C(22)H(18)N(2)O(4))Cl(2)(C(2)H(6)OS)]·C(3)H(7)NO, the Zn(II) atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The Pb(II) atom is coordinated in a distorted octa­hedral geometry by the four O atoms of the diphenolate ligand, one O atom from the dimethyl sulfoxide mol­ecule and one Cl atom. The dimethyl sulfoxide mol­ecule is disordered over two positions, with site occupancies of 0.576 (2) and 0.424 (2).
format Text
id pubmed-2959625
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29596252010-12-30 Dichlorido{μ-6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethyl­formamide solvate Wang, Hailong Zhang, Daopeng Tian, Laijin Zhang, Li-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the heterodinuclear complex of the title compound, [PbZn(C(22)H(18)N(2)O(4))Cl(2)(C(2)H(6)OS)]·C(3)H(7)NO, the Zn(II) atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The Pb(II) atom is coordinated in a distorted octa­hedral geometry by the four O atoms of the diphenolate ligand, one O atom from the dimethyl sulfoxide mol­ecule and one Cl atom. The dimethyl sulfoxide mol­ecule is disordered over two positions, with site occupancies of 0.576 (2) and 0.424 (2). International Union of Crystallography 2008-10-25 /pmc/articles/PMC2959625/ /pubmed/21580898 http://dx.doi.org/10.1107/S1600536808034338 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Hailong
Zhang, Daopeng
Tian, Laijin
Zhang, Li-Fang
Dichlorido{μ-6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethyl­formamide solvate
title Dichlorido{μ-6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethyl­formamide solvate
title_full Dichlorido{μ-6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethyl­formamide solvate
title_fullStr Dichlorido{μ-6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethyl­formamide solvate
title_full_unstemmed Dichlorido{μ-6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethyl­formamide solvate
title_short Dichlorido{μ-6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethyl­formamide solvate
title_sort dichlorido{μ-6,6′-dimeth­oxy-2,2′-[o-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}(dimethyl sulfoxide)lead(ii)zinc(ii) n,n-dimethyl­formamide solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959625/
https://www.ncbi.nlm.nih.gov/pubmed/21580898
http://dx.doi.org/10.1107/S1600536808034338
work_keys_str_mv AT wanghailong dichloridom66dimethoxy22ophenylenebisnitrilomethylidynediphenolatodimethylsulfoxideleadiizinciinndimethylformamidesolvate
AT zhangdaopeng dichloridom66dimethoxy22ophenylenebisnitrilomethylidynediphenolatodimethylsulfoxideleadiizinciinndimethylformamidesolvate
AT tianlaijin dichloridom66dimethoxy22ophenylenebisnitrilomethylidynediphenolatodimethylsulfoxideleadiizinciinndimethylformamidesolvate
AT zhanglifang dichloridom66dimethoxy22ophenylenebisnitrilomethylidynediphenolatodimethylsulfoxideleadiizinciinndimethylformamidesolvate

Ejemplares similares