Cargando…
Bis{6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolato-κ(2) O,O′}bis(nitrato-κ(2) O,O′)cadmium(II)
The Schiff base 6-methoxy-2-[(4-methylphenyl)iminomethyl]phenol (HL) forms a neutral complex with cadmium(II) nitrate, [Cd(NO(3))(2)(C(15)H(15)NO(2))(2)], in which the four O atoms of the two independent ligands are coordinated to the metal center and the protonated imine N atoms are involved...
| Autores principales: | , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959626/ https://www.ncbi.nlm.nih.gov/pubmed/21580914 http://dx.doi.org/10.1107/S1600536808033539 |
| _version_ | 1782188544778829824 |
|---|---|
| author | Li, Hua-Qiong Xian, Hui-Duo Liu, Jian-Feng Zhao, Guo-Liang |
| author_facet | Li, Hua-Qiong Xian, Hui-Duo Liu, Jian-Feng Zhao, Guo-Liang |
| author_sort | Li, Hua-Qiong |
| collection | PubMed |
| description | The Schiff base 6-methoxy-2-[(4-methylphenyl)iminomethyl]phenol (HL) forms a neutral complex with cadmium(II) nitrate, [Cd(NO(3))(2)(C(15)H(15)NO(2))(2)], in which the four O atoms of the two independent ligands are coordinated to the metal center and the protonated imine N atoms are involved in a hydrogen bond with the phenoxide group. Intramolecular N—H⋯O hydrogen-bonding interactions stabilize the structure. Each organic ligand assumes a zwitterionic form, chelating to the metal atom through the two O atoms, while the two nitrate groups also exhibit chelating behavior, leading to a distorted octahedral coordination of the Cd atom. |
| format | Text |
| id | pubmed-2959626 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29596262010-12-30 Bis{6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolato-κ(2) O,O′}bis(nitrato-κ(2) O,O′)cadmium(II) Li, Hua-Qiong Xian, Hui-Duo Liu, Jian-Feng Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Schiff base 6-methoxy-2-[(4-methylphenyl)iminomethyl]phenol (HL) forms a neutral complex with cadmium(II) nitrate, [Cd(NO(3))(2)(C(15)H(15)NO(2))(2)], in which the four O atoms of the two independent ligands are coordinated to the metal center and the protonated imine N atoms are involved in a hydrogen bond with the phenoxide group. Intramolecular N—H⋯O hydrogen-bonding interactions stabilize the structure. Each organic ligand assumes a zwitterionic form, chelating to the metal atom through the two O atoms, while the two nitrate groups also exhibit chelating behavior, leading to a distorted octahedral coordination of the Cd atom. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959626/ /pubmed/21580914 http://dx.doi.org/10.1107/S1600536808033539 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Hua-Qiong Xian, Hui-Duo Liu, Jian-Feng Zhao, Guo-Liang Bis{6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolato-κ(2) O,O′}bis(nitrato-κ(2) O,O′)cadmium(II) |
| title | Bis{6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}bis(nitrato-κ(2)
O,O′)cadmium(II) |
| title_full | Bis{6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}bis(nitrato-κ(2)
O,O′)cadmium(II) |
| title_fullStr | Bis{6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}bis(nitrato-κ(2)
O,O′)cadmium(II) |
| title_full_unstemmed | Bis{6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}bis(nitrato-κ(2)
O,O′)cadmium(II) |
| title_short | Bis{6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}bis(nitrato-κ(2)
O,O′)cadmium(II) |
| title_sort | bis{6-methoxy-2-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
o,o′}bis(nitrato-κ(2)
o,o′)cadmium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959626/ https://www.ncbi.nlm.nih.gov/pubmed/21580914 http://dx.doi.org/10.1107/S1600536808033539 |
| work_keys_str_mv | AT lihuaqiong bis6methoxy24methylphenyliminiomethylphenolatok2oobisnitratok2oocadmiumii AT xianhuiduo bis6methoxy24methylphenyliminiomethylphenolatok2oobisnitratok2oocadmiumii AT liujianfeng bis6methoxy24methylphenyliminiomethylphenolatok2oobisnitratok2oocadmiumii AT zhaoguoliang bis6methoxy24methylphenyliminiomethylphenolatok2oobisnitratok2oocadmiumii |