Tetra­kis[tris­(2,2′-bi-1H-benzimidazole)nickel(II)] bis­(phosphate) sulfate

The title compound, [Ni(C(14)H(10)N(4))(3)](4)(PO(4))(2)(SO(4)), consists of [Ni(C(14)H(10)N(4))(3)](2+) complex cations (.3. symmetry) and disordered anions ([Image: see text] symmetry) with occupancy factors of two-thirds for PO(4) (3−) and one-third for SO(4) (2−). The Ni(2+) centre is chelated b...

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Detalles Bibliográficos
Autores principales: Ling, Chun-Sheng, Yan, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959627/
https://www.ncbi.nlm.nih.gov/pubmed/21580849
http://dx.doi.org/10.1107/S1600536808032571
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author Ling, Chun-Sheng
Yan, Lin
author_facet Ling, Chun-Sheng
Yan, Lin
author_sort Ling, Chun-Sheng
collection PubMed
description The title compound, [Ni(C(14)H(10)N(4))(3)](4)(PO(4))(2)(SO(4)), consists of [Ni(C(14)H(10)N(4))(3)](2+) complex cations (.3. symmetry) and disordered anions ([Image: see text] symmetry) with occupancy factors of two-thirds for PO(4) (3−) and one-third for SO(4) (2−). The Ni(2+) centre is chelated by three bidentate 2,2′-bi-1H-benzimidazole mol­ecules in a distorted octa­hedral coordination. N—H⋯O hydrogen bonds consolidate the building units into a framework structure.
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spelling pubmed-29596272010-12-30 Tetra­kis[tris­(2,2′-bi-1H-benzimidazole)nickel(II)] bis­(phosphate) sulfate Ling, Chun-Sheng Yan, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(14)H(10)N(4))(3)](4)(PO(4))(2)(SO(4)), consists of [Ni(C(14)H(10)N(4))(3)](2+) complex cations (.3. symmetry) and disordered anions ([Image: see text] symmetry) with occupancy factors of two-thirds for PO(4) (3−) and one-third for SO(4) (2−). The Ni(2+) centre is chelated by three bidentate 2,2′-bi-1H-benzimidazole mol­ecules in a distorted octa­hedral coordination. N—H⋯O hydrogen bonds consolidate the building units into a framework structure. International Union of Crystallography 2008-10-15 /pmc/articles/PMC2959627/ /pubmed/21580849 http://dx.doi.org/10.1107/S1600536808032571 Text en © Ling and Lin 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ling, Chun-Sheng
Yan, Lin
Tetra­kis[tris­(2,2′-bi-1H-benzimidazole)nickel(II)] bis­(phosphate) sulfate
title Tetra­kis[tris­(2,2′-bi-1H-benzimidazole)nickel(II)] bis­(phosphate) sulfate
title_full Tetra­kis[tris­(2,2′-bi-1H-benzimidazole)nickel(II)] bis­(phosphate) sulfate
title_fullStr Tetra­kis[tris­(2,2′-bi-1H-benzimidazole)nickel(II)] bis­(phosphate) sulfate
title_full_unstemmed Tetra­kis[tris­(2,2′-bi-1H-benzimidazole)nickel(II)] bis­(phosphate) sulfate
title_short Tetra­kis[tris­(2,2′-bi-1H-benzimidazole)nickel(II)] bis­(phosphate) sulfate
title_sort tetra­kis[tris­(2,2′-bi-1h-benzimidazole)nickel(ii)] bis­(phosphate) sulfate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959627/
https://www.ncbi.nlm.nih.gov/pubmed/21580849
http://dx.doi.org/10.1107/S1600536808032571
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AT yanlin tetrakistris22bi1hbenzimidazolenickeliibisphosphatesulfate

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