(E)-1,1′-Bis[(E)-but-2-en­yl]-3,3′-(propane-1,3-di­yl)bis­(1H-benzimidazol-3-ium) dibromide monohydrate

The title compound, C(25)H(30)N(4) (2+)·2Br(−)·H(2)O, was synthesized from 1,1′-propyl­enedibenzimidazole and (E)-1-bromo­but-2-ene in dimethyl­formamide solution. The two benzimidazole ring systems are essentially planar, with maximum deviations of 0.011 (4) and 0.023 (3) Å. The dihedral angle betw...

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Detalles Bibliográficos
Autores principales: Akkurt, Mehmet, Yıldırım, Sema Öztürk, Şireci, Nihat, Küçükbay, Hasan, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959630/
https://www.ncbi.nlm.nih.gov/pubmed/21580997
http://dx.doi.org/10.1107/S160053680803095X
Descripción
Sumario:The title compound, C(25)H(30)N(4) (2+)·2Br(−)·H(2)O, was synthesized from 1,1′-propyl­enedibenzimidazole and (E)-1-bromo­but-2-ene in dimethyl­formamide solution. The two benzimidazole ring systems are essentially planar, with maximum deviations of 0.011 (4) and 0.023 (3) Å. The dihedral angle between these two ring systems is 25.87 (15)°. The crystal structure is stabilized by inter­molecular O—H⋯Br and C—H⋯Br hydrogen-bonding inter­actions. Atmospheric water was incorporated into the crystal structure.

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