(E)-1,1′-Bis[(E)-but-2-en­yl]-3,3′-(propane-1,3-di­yl)bis­(1H-benzimidazol-3-ium) dibromide monohydrate

The title compound, C(25)H(30)N(4) (2+)·2Br(−)·H(2)O, was synthesized from 1,1′-propyl­enedibenzimidazole and (E)-1-bromo­but-2-ene in dimethyl­formamide solution. The two benzimidazole ring systems are essentially planar, with maximum deviations of 0.011 (4) and 0.023 (3) Å. The dihedral angle betw...

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Autores principales: Akkurt, Mehmet, Yıldırım, Sema Öztürk, Şireci, Nihat, Küçükbay, Hasan, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959630/
https://www.ncbi.nlm.nih.gov/pubmed/21580997
http://dx.doi.org/10.1107/S160053680803095X
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author Akkurt, Mehmet
Yıldırım, Sema Öztürk
Şireci, Nihat
Küçükbay, Hasan
Büyükgüngör, Orhan
author_facet Akkurt, Mehmet
Yıldırım, Sema Öztürk
Şireci, Nihat
Küçükbay, Hasan
Büyükgüngör, Orhan
author_sort Akkurt, Mehmet
collection PubMed
description The title compound, C(25)H(30)N(4) (2+)·2Br(−)·H(2)O, was synthesized from 1,1′-propyl­enedibenzimidazole and (E)-1-bromo­but-2-ene in dimethyl­formamide solution. The two benzimidazole ring systems are essentially planar, with maximum deviations of 0.011 (4) and 0.023 (3) Å. The dihedral angle between these two ring systems is 25.87 (15)°. The crystal structure is stabilized by inter­molecular O—H⋯Br and C—H⋯Br hydrogen-bonding inter­actions. Atmospheric water was incorporated into the crystal structure.
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spelling pubmed-29596302010-12-30 (E)-1,1′-Bis[(E)-but-2-en­yl]-3,3′-(propane-1,3-di­yl)bis­(1H-benzimidazol-3-ium) dibromide monohydrate Akkurt, Mehmet Yıldırım, Sema Öztürk Şireci, Nihat Küçükbay, Hasan Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(25)H(30)N(4) (2+)·2Br(−)·H(2)O, was synthesized from 1,1′-propyl­enedibenzimidazole and (E)-1-bromo­but-2-ene in dimethyl­formamide solution. The two benzimidazole ring systems are essentially planar, with maximum deviations of 0.011 (4) and 0.023 (3) Å. The dihedral angle between these two ring systems is 25.87 (15)°. The crystal structure is stabilized by inter­molecular O—H⋯Br and C—H⋯Br hydrogen-bonding inter­actions. Atmospheric water was incorporated into the crystal structure. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959630/ /pubmed/21580997 http://dx.doi.org/10.1107/S160053680803095X Text en © Akkurt et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Yıldırım, Sema Öztürk
Şireci, Nihat
Küçükbay, Hasan
Büyükgüngör, Orhan
(E)-1,1′-Bis[(E)-but-2-en­yl]-3,3′-(propane-1,3-di­yl)bis­(1H-benzimidazol-3-ium) dibromide monohydrate
title (E)-1,1′-Bis[(E)-but-2-en­yl]-3,3′-(propane-1,3-di­yl)bis­(1H-benzimidazol-3-ium) dibromide monohydrate
title_full (E)-1,1′-Bis[(E)-but-2-en­yl]-3,3′-(propane-1,3-di­yl)bis­(1H-benzimidazol-3-ium) dibromide monohydrate
title_fullStr (E)-1,1′-Bis[(E)-but-2-en­yl]-3,3′-(propane-1,3-di­yl)bis­(1H-benzimidazol-3-ium) dibromide monohydrate
title_full_unstemmed (E)-1,1′-Bis[(E)-but-2-en­yl]-3,3′-(propane-1,3-di­yl)bis­(1H-benzimidazol-3-ium) dibromide monohydrate
title_short (E)-1,1′-Bis[(E)-but-2-en­yl]-3,3′-(propane-1,3-di­yl)bis­(1H-benzimidazol-3-ium) dibromide monohydrate
title_sort (e)-1,1′-bis[(e)-but-2-en­yl]-3,3′-(propane-1,3-di­yl)bis­(1h-benzimidazol-3-ium) dibromide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959630/
https://www.ncbi.nlm.nih.gov/pubmed/21580997
http://dx.doi.org/10.1107/S160053680803095X
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