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[(–)-(1S,2S)-N,N′-Bis(2-oxidobenzylidene)-1,2-diphenylethane-1,2-diamine]bis(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate
In the title compound, [Co(C(28)H(22)N(2)O(2))(C(5)H(5)N)(2)]ClO(4)·0.5CH(4)O·0.5H(2)O, each Co(III) ion is coordinated by the tetradentate N,N′-bis(2-oxidobenzylidene)-1,2-diphenylethane-1,2-diamine ligand [Co—N = 1.900 (3) and 1.903 (3) Å; Co—O = 1.885 (3) and 1.891 (3) Å] and two pyridine lig...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959631/ https://www.ncbi.nlm.nih.gov/pubmed/21580833 http://dx.doi.org/10.1107/S1600536808031887 |
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author | Chen, Yu-Ting |
author_facet | Chen, Yu-Ting |
author_sort | Chen, Yu-Ting |
collection | PubMed |
description | In the title compound, [Co(C(28)H(22)N(2)O(2))(C(5)H(5)N)(2)]ClO(4)·0.5CH(4)O·0.5H(2)O, each Co(III) ion is coordinated by the tetradentate N,N′-bis(2-oxidobenzylidene)-1,2-diphenylethane-1,2-diamine ligand [Co—N = 1.900 (3) and 1.903 (3) Å; Co—O = 1.885 (3) and 1.891 (3) Å] and two pyridine ligands [Co—N = 1.967 (4) and 1.977 (3) Å] in a distorted octahedral geometry. The packing of the cations and anions forms voids of 258 Å(3), which are filled by methanol and solvent water molecules with half occupancies. O—H⋯O hydrogen bonds between solvent molecules, perchlorate anions and water molecules, and between water molecules and O atoms of the ligand, help to consolidate the crystal packing. |
format | Text |
id | pubmed-2959631 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29596312010-12-30 [(–)-(1S,2S)-N,N′-Bis(2-oxidobenzylidene)-1,2-diphenylethane-1,2-diamine]bis(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate Chen, Yu-Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(28)H(22)N(2)O(2))(C(5)H(5)N)(2)]ClO(4)·0.5CH(4)O·0.5H(2)O, each Co(III) ion is coordinated by the tetradentate N,N′-bis(2-oxidobenzylidene)-1,2-diphenylethane-1,2-diamine ligand [Co—N = 1.900 (3) and 1.903 (3) Å; Co—O = 1.885 (3) and 1.891 (3) Å] and two pyridine ligands [Co—N = 1.967 (4) and 1.977 (3) Å] in a distorted octahedral geometry. The packing of the cations and anions forms voids of 258 Å(3), which are filled by methanol and solvent water molecules with half occupancies. O—H⋯O hydrogen bonds between solvent molecules, perchlorate anions and water molecules, and between water molecules and O atoms of the ligand, help to consolidate the crystal packing. International Union of Crystallography 2008-10-09 /pmc/articles/PMC2959631/ /pubmed/21580833 http://dx.doi.org/10.1107/S1600536808031887 Text en © Yu-Ting Chen 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Yu-Ting [(–)-(1S,2S)-N,N′-Bis(2-oxidobenzylidene)-1,2-diphenylethane-1,2-diamine]bis(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate |
title | [(–)-(1S,2S)-N,N′-Bis(2-oxidobenzylidene)-1,2-diphenylethane-1,2-diamine]bis(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate |
title_full | [(–)-(1S,2S)-N,N′-Bis(2-oxidobenzylidene)-1,2-diphenylethane-1,2-diamine]bis(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate |
title_fullStr | [(–)-(1S,2S)-N,N′-Bis(2-oxidobenzylidene)-1,2-diphenylethane-1,2-diamine]bis(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate |
title_full_unstemmed | [(–)-(1S,2S)-N,N′-Bis(2-oxidobenzylidene)-1,2-diphenylethane-1,2-diamine]bis(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate |
title_short | [(–)-(1S,2S)-N,N′-Bis(2-oxidobenzylidene)-1,2-diphenylethane-1,2-diamine]bis(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate |
title_sort | [(–)-(1s,2s)-n,n′-bis(2-oxidobenzylidene)-1,2-diphenylethane-1,2-diamine]bis(pyridine)cobalt(iii) perchlorate methanol hemisolvate hemihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959631/ https://www.ncbi.nlm.nih.gov/pubmed/21580833 http://dx.doi.org/10.1107/S1600536808031887 |
work_keys_str_mv | AT chenyuting 1s2snnbis2oxidobenzylidene12diphenylethane12diaminebispyridinecobaltiiiperchloratemethanolhemisolvatehemihydrate |