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[(–)-(1S,2S)-N,N′-Bis(2-oxidobenzyl­idene)-1,2-diphenyl­ethane-1,2-diamine]­bis­(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate

In the title compound, [Co(C(28)H(22)N(2)O(2))(C(5)H(5)N)(2)]ClO(4)·0.5CH(4)O·0.5H(2)O, each Co(III) ion is coordinated by the tetra­dentate N,N′-bis­(2-oxidobenzyl­idene)-1,2-diphenyl­ethane-1,2-diamine ligand [Co—N = 1.900 (3) and 1.903 (3) Å; Co—O = 1.885 (3) and 1.891 (3) Å] and two pyridine lig...

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Detalles Bibliográficos
Autor principal: Chen, Yu-Ting
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959631/
https://www.ncbi.nlm.nih.gov/pubmed/21580833
http://dx.doi.org/10.1107/S1600536808031887
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author Chen, Yu-Ting
author_facet Chen, Yu-Ting
author_sort Chen, Yu-Ting
collection PubMed
description In the title compound, [Co(C(28)H(22)N(2)O(2))(C(5)H(5)N)(2)]ClO(4)·0.5CH(4)O·0.5H(2)O, each Co(III) ion is coordinated by the tetra­dentate N,N′-bis­(2-oxidobenzyl­idene)-1,2-diphenyl­ethane-1,2-diamine ligand [Co—N = 1.900 (3) and 1.903 (3) Å; Co—O = 1.885 (3) and 1.891 (3) Å] and two pyridine ligands [Co—N = 1.967 (4) and 1.977 (3) Å] in a distorted octa­hedral geometry. The packing of the cations and anions forms voids of 258 Å(3), which are filled by methanol and solvent water mol­ecules with half occupancies. O—H⋯O hydrogen bonds between solvent molecules, perchlorate anions and water molecules, and between water molecules and O atoms of the ligand, help to consolidate the crystal packing.
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spelling pubmed-29596312010-12-30 [(–)-(1S,2S)-N,N′-Bis(2-oxidobenzyl­idene)-1,2-diphenyl­ethane-1,2-diamine]­bis­(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate Chen, Yu-Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(28)H(22)N(2)O(2))(C(5)H(5)N)(2)]ClO(4)·0.5CH(4)O·0.5H(2)O, each Co(III) ion is coordinated by the tetra­dentate N,N′-bis­(2-oxidobenzyl­idene)-1,2-diphenyl­ethane-1,2-diamine ligand [Co—N = 1.900 (3) and 1.903 (3) Å; Co—O = 1.885 (3) and 1.891 (3) Å] and two pyridine ligands [Co—N = 1.967 (4) and 1.977 (3) Å] in a distorted octa­hedral geometry. The packing of the cations and anions forms voids of 258 Å(3), which are filled by methanol and solvent water mol­ecules with half occupancies. O—H⋯O hydrogen bonds between solvent molecules, perchlorate anions and water molecules, and between water molecules and O atoms of the ligand, help to consolidate the crystal packing. International Union of Crystallography 2008-10-09 /pmc/articles/PMC2959631/ /pubmed/21580833 http://dx.doi.org/10.1107/S1600536808031887 Text en © Yu-Ting Chen 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Yu-Ting
[(–)-(1S,2S)-N,N′-Bis(2-oxidobenzyl­idene)-1,2-diphenyl­ethane-1,2-diamine]­bis­(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate
title [(–)-(1S,2S)-N,N′-Bis(2-oxidobenzyl­idene)-1,2-diphenyl­ethane-1,2-diamine]­bis­(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate
title_full [(–)-(1S,2S)-N,N′-Bis(2-oxidobenzyl­idene)-1,2-diphenyl­ethane-1,2-diamine]­bis­(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate
title_fullStr [(–)-(1S,2S)-N,N′-Bis(2-oxidobenzyl­idene)-1,2-diphenyl­ethane-1,2-diamine]­bis­(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate
title_full_unstemmed [(–)-(1S,2S)-N,N′-Bis(2-oxidobenzyl­idene)-1,2-diphenyl­ethane-1,2-diamine]­bis­(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate
title_short [(–)-(1S,2S)-N,N′-Bis(2-oxidobenzyl­idene)-1,2-diphenyl­ethane-1,2-diamine]­bis­(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate
title_sort [(–)-(1s,2s)-n,n′-bis(2-oxidobenzyl­idene)-1,2-diphenyl­ethane-1,2-diamine]­bis­(pyridine)cobalt(iii) perchlorate methanol hemisolvate hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959631/
https://www.ncbi.nlm.nih.gov/pubmed/21580833
http://dx.doi.org/10.1107/S1600536808031887
work_keys_str_mv AT chenyuting 1s2snnbis2oxidobenzylidene12diphenylethane12diaminebispyridinecobaltiiiperchloratemethanolhemisolvatehemihydrate