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(E)-4-Bromo-N′-(2-hydroxy-1-naphthylmethylene)benzohydrazide
The title compound, C(18)H(13)BrN(2)O(2), was synthesized by the reaction of 2-hydroxy-1-naphthaldehyde with 4-bromobenzohydrazide. This Schiff base molecule has an E configuration about the C=N bond and is almost planar, the dihedral angle between the mean planes through the substituted benzene...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959633/ https://www.ncbi.nlm.nih.gov/pubmed/21580936 http://dx.doi.org/10.1107/S1600536808031395 |
Sumario: | The title compound, C(18)H(13)BrN(2)O(2), was synthesized by the reaction of 2-hydroxy-1-naphthaldehyde with 4-bromobenzohydrazide. This Schiff base molecule has an E configuration about the C=N bond and is almost planar, the dihedral angle between the mean planes through the substituted benzene ring and the naphthyl system being 6.6 (2)°. There is an intramolecular O—H⋯N hydrogen bond involving the naphthyl hydroxy substituent and the N′ atom of the hydrazide group. In the crystal structure, molecules are linked through intermolecular N—-H⋯O hydrogen bonds to form chains extending along the b direction. |
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