(E)-4-Bromo-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide

The title compound, C(18)H(13)BrN(2)O(2), was synthesized by the reaction of 2-hydr­oxy-1-naphthaldehyde with 4-bromo­benzohydrazide. This Schiff base mol­ecule has an E configuration about the C=N bond and is almost planar, the dihedral angle between the mean planes through the substituted benzene...

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Detalles Bibliográficos
Autores principales: Diao, Yun-Peng, Zhang, Qi-Hui, Wang, Da-Cheng, Deng, Xu-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959633/
https://www.ncbi.nlm.nih.gov/pubmed/21580936
http://dx.doi.org/10.1107/S1600536808031395
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author Diao, Yun-Peng
Zhang, Qi-Hui
Wang, Da-Cheng
Deng, Xu-Ming
author_facet Diao, Yun-Peng
Zhang, Qi-Hui
Wang, Da-Cheng
Deng, Xu-Ming
author_sort Diao, Yun-Peng
collection PubMed
description The title compound, C(18)H(13)BrN(2)O(2), was synthesized by the reaction of 2-hydr­oxy-1-naphthaldehyde with 4-bromo­benzohydrazide. This Schiff base mol­ecule has an E configuration about the C=N bond and is almost planar, the dihedral angle between the mean planes through the substituted benzene ring and the naphthyl system being 6.6 (2)°. There is an intra­molecular O—H⋯N hydrogen bond involving the naphthyl hydr­oxy substituent and the N′ atom of the hydrazide group. In the crystal structure, mol­ecules are linked through inter­molecular N—-H⋯O hydrogen bonds to form chains extending along the b direction.
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spelling pubmed-29596332010-12-30 (E)-4-Bromo-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide Diao, Yun-Peng Zhang, Qi-Hui Wang, Da-Cheng Deng, Xu-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(13)BrN(2)O(2), was synthesized by the reaction of 2-hydr­oxy-1-naphthaldehyde with 4-bromo­benzohydrazide. This Schiff base mol­ecule has an E configuration about the C=N bond and is almost planar, the dihedral angle between the mean planes through the substituted benzene ring and the naphthyl system being 6.6 (2)°. There is an intra­molecular O—H⋯N hydrogen bond involving the naphthyl hydr­oxy substituent and the N′ atom of the hydrazide group. In the crystal structure, mol­ecules are linked through inter­molecular N—-H⋯O hydrogen bonds to form chains extending along the b direction. International Union of Crystallography 2008-10-04 /pmc/articles/PMC2959633/ /pubmed/21580936 http://dx.doi.org/10.1107/S1600536808031395 Text en © Diao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Diao, Yun-Peng
Zhang, Qi-Hui
Wang, Da-Cheng
Deng, Xu-Ming
(E)-4-Bromo-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide
title (E)-4-Bromo-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide
title_full (E)-4-Bromo-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide
title_fullStr (E)-4-Bromo-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide
title_full_unstemmed (E)-4-Bromo-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide
title_short (E)-4-Bromo-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide
title_sort (e)-4-bromo-n′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959633/
https://www.ncbi.nlm.nih.gov/pubmed/21580936
http://dx.doi.org/10.1107/S1600536808031395
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