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(Benzophenone imine-κN)chlorido(hydridotripyrazolylborato)(triphenylphosphine)ruthenium(II) diethyl ether solvate
The reaction of RuCl(Tp)(Ph(3)P)(2), where Tp is [(CH)(3)N(2)](3)BH, with benzophenone imine leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(13)H(11)N)(C(18)H(15)P)]·C(4)H(10)O. The environment about the Ru atom corresponds to a slightly distorted octahedron and the bite angle...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959639/ https://www.ncbi.nlm.nih.gov/pubmed/21580892 http://dx.doi.org/10.1107/S1600536808033722 |
| _version_ | 1782188547857448960 |
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| author | Tong, Hung-Chun Hsu, Chih-Yung Chen Lo, Yih-Hsing Lin, Chia-Her Wang, Yu |
| author_facet | Tong, Hung-Chun Hsu, Chih-Yung Chen Lo, Yih-Hsing Lin, Chia-Her Wang, Yu |
| author_sort | Tong, Hung-Chun |
| collection | PubMed |
| description | The reaction of RuCl(Tp)(Ph(3)P)(2), where Tp is [(CH)(3)N(2)](3)BH, with benzophenone imine leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(13)H(11)N)(C(18)H(15)P)]·C(4)H(10)O. The environment about the Ru atom corresponds to a slightly distorted octahedron and the bite angle of the Tp ligand produces an average N—Ru—N angle of 86.3 (9)°. The three Ru—N(Tp) bond lengths [2.117 (2), 2.079 (2) and 2.084 (2) Å] are slightly longer than the average distance (2.038 Å) in other ruthenium–Tp complexes. |
| format | Text |
| id | pubmed-2959639 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29596392010-12-30 (Benzophenone imine-κN)chlorido(hydridotripyrazolylborato)(triphenylphosphine)ruthenium(II) diethyl ether solvate Tong, Hung-Chun Hsu, Chih-Yung Chen Lo, Yih-Hsing Lin, Chia-Her Wang, Yu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of RuCl(Tp)(Ph(3)P)(2), where Tp is [(CH)(3)N(2)](3)BH, with benzophenone imine leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(13)H(11)N)(C(18)H(15)P)]·C(4)H(10)O. The environment about the Ru atom corresponds to a slightly distorted octahedron and the bite angle of the Tp ligand produces an average N—Ru—N angle of 86.3 (9)°. The three Ru—N(Tp) bond lengths [2.117 (2), 2.079 (2) and 2.084 (2) Å] are slightly longer than the average distance (2.038 Å) in other ruthenium–Tp complexes. International Union of Crystallography 2008-10-22 /pmc/articles/PMC2959639/ /pubmed/21580892 http://dx.doi.org/10.1107/S1600536808033722 Text en © Tong et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Tong, Hung-Chun Hsu, Chih-Yung Chen Lo, Yih-Hsing Lin, Chia-Her Wang, Yu (Benzophenone imine-κN)chlorido(hydridotripyrazolylborato)(triphenylphosphine)ruthenium(II) diethyl ether solvate |
| title | (Benzophenone imine-κN)chlorido(hydridotripyrazolylborato)(triphenylphosphine)ruthenium(II) diethyl ether solvate |
| title_full | (Benzophenone imine-κN)chlorido(hydridotripyrazolylborato)(triphenylphosphine)ruthenium(II) diethyl ether solvate |
| title_fullStr | (Benzophenone imine-κN)chlorido(hydridotripyrazolylborato)(triphenylphosphine)ruthenium(II) diethyl ether solvate |
| title_full_unstemmed | (Benzophenone imine-κN)chlorido(hydridotripyrazolylborato)(triphenylphosphine)ruthenium(II) diethyl ether solvate |
| title_short | (Benzophenone imine-κN)chlorido(hydridotripyrazolylborato)(triphenylphosphine)ruthenium(II) diethyl ether solvate |
| title_sort | (benzophenone imine-κn)chlorido(hydridotripyrazolylborato)(triphenylphosphine)ruthenium(ii) diethyl ether solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959639/ https://www.ncbi.nlm.nih.gov/pubmed/21580892 http://dx.doi.org/10.1107/S1600536808033722 |
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