Triaqua­(N (2),N (4)-di-2-pyridylpyrimidine-2,4-diamine)cobalt(II) fumarate

The Co atom in the title compound, [Co(C(14)H(12)N(6))(H(2)O)(3)]C(4)H(2)O(4), has a mer-CoN(3)O(3) octa­hedral coordination arising from the tridentate N (2),N (4)-di-2-pyridylpyrimidine-2,4-diamine (tpda) ligand and three coordinated water mol­ecules. The asymmetric unit contains two fumarate half...

Descripción completa

Detalles Bibliográficos
Autor principal: Yang, Ming-hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959641/
https://www.ncbi.nlm.nih.gov/pubmed/21580856
http://dx.doi.org/10.1107/S1600536808032613
_version_ 1782188548336648192
author Yang, Ming-hua
author_facet Yang, Ming-hua
author_sort Yang, Ming-hua
collection PubMed
description The Co atom in the title compound, [Co(C(14)H(12)N(6))(H(2)O)(3)]C(4)H(2)O(4), has a mer-CoN(3)O(3) octa­hedral coordination arising from the tridentate N (2),N (4)-di-2-pyridylpyrimidine-2,4-diamine (tpda) ligand and three coordinated water mol­ecules. The asymmetric unit contains two fumarate half-anions, both completed by inversion symmetry. A network of N—H⋯O and O—H⋯O hydrogen bonds leads to a three-dimensional network in the crystal structure.
format Text
id pubmed-2959641
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29596412010-12-30 Triaqua­(N (2),N (4)-di-2-pyridylpyrimidine-2,4-diamine)cobalt(II) fumarate Yang, Ming-hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co atom in the title compound, [Co(C(14)H(12)N(6))(H(2)O)(3)]C(4)H(2)O(4), has a mer-CoN(3)O(3) octa­hedral coordination arising from the tridentate N (2),N (4)-di-2-pyridylpyrimidine-2,4-diamine (tpda) ligand and three coordinated water mol­ecules. The asymmetric unit contains two fumarate half-anions, both completed by inversion symmetry. A network of N—H⋯O and O—H⋯O hydrogen bonds leads to a three-dimensional network in the crystal structure. International Union of Crystallography 2008-10-15 /pmc/articles/PMC2959641/ /pubmed/21580856 http://dx.doi.org/10.1107/S1600536808032613 Text en © Ming-hua Yang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Ming-hua
Triaqua­(N (2),N (4)-di-2-pyridylpyrimidine-2,4-diamine)cobalt(II) fumarate
title Triaqua­(N (2),N (4)-di-2-pyridylpyrimidine-2,4-diamine)cobalt(II) fumarate
title_full Triaqua­(N (2),N (4)-di-2-pyridylpyrimidine-2,4-diamine)cobalt(II) fumarate
title_fullStr Triaqua­(N (2),N (4)-di-2-pyridylpyrimidine-2,4-diamine)cobalt(II) fumarate
title_full_unstemmed Triaqua­(N (2),N (4)-di-2-pyridylpyrimidine-2,4-diamine)cobalt(II) fumarate
title_short Triaqua­(N (2),N (4)-di-2-pyridylpyrimidine-2,4-diamine)cobalt(II) fumarate
title_sort triaqua­(n (2),n (4)-di-2-pyridylpyrimidine-2,4-diamine)cobalt(ii) fumarate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959641/
https://www.ncbi.nlm.nih.gov/pubmed/21580856
http://dx.doi.org/10.1107/S1600536808032613
work_keys_str_mv AT yangminghua triaquan2n4di2pyridylpyrimidine24diaminecobaltiifumarate

Ejemplares similares