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An orthorhombic polymorph of cerium(III) ultraphosphate, CeP(5)O(14)
Cerium(III) ultraphosphate, CeP(5)O(14), was synthesized by a high-temperature solution reaction between CeO(2) and NH(4)H(2)PO(4) in a Ce–P molar ratio of 1:12. Colourless crystals of the orthorhombic polymorph were obtained by cooling the melt of the mixture. The structure contains (P(5)O(14))(3...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959646/ https://www.ncbi.nlm.nih.gov/pubmed/21580810 http://dx.doi.org/10.1107/S1600536808032972 |
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author | Zhu, Jing Cheng, Wen-Dan Zhang, Hao |
author_facet | Zhu, Jing Cheng, Wen-Dan Zhang, Hao |
author_sort | Zhu, Jing |
collection | PubMed |
description | Cerium(III) ultraphosphate, CeP(5)O(14), was synthesized by a high-temperature solution reaction between CeO(2) and NH(4)H(2)PO(4) in a Ce–P molar ratio of 1:12. Colourless crystals of the orthorhombic polymorph were obtained by cooling the melt of the mixture. The structure contains (P(5)O(14))(3−) anionic ribbons linked by distorted CeO(8) polyhedra. |
format | Text |
id | pubmed-2959646 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29596462010-12-30 An orthorhombic polymorph of cerium(III) ultraphosphate, CeP(5)O(14) Zhu, Jing Cheng, Wen-Dan Zhang, Hao Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Cerium(III) ultraphosphate, CeP(5)O(14), was synthesized by a high-temperature solution reaction between CeO(2) and NH(4)H(2)PO(4) in a Ce–P molar ratio of 1:12. Colourless crystals of the orthorhombic polymorph were obtained by cooling the melt of the mixture. The structure contains (P(5)O(14))(3−) anionic ribbons linked by distorted CeO(8) polyhedra. International Union of Crystallography 2008-10-15 /pmc/articles/PMC2959646/ /pubmed/21580810 http://dx.doi.org/10.1107/S1600536808032972 Text en © Zhu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Inorganic Papers Zhu, Jing Cheng, Wen-Dan Zhang, Hao An orthorhombic polymorph of cerium(III) ultraphosphate, CeP(5)O(14) |
title | An orthorhombic polymorph of cerium(III) ultraphosphate, CeP(5)O(14)
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title_full | An orthorhombic polymorph of cerium(III) ultraphosphate, CeP(5)O(14)
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title_fullStr | An orthorhombic polymorph of cerium(III) ultraphosphate, CeP(5)O(14)
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title_full_unstemmed | An orthorhombic polymorph of cerium(III) ultraphosphate, CeP(5)O(14)
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title_short | An orthorhombic polymorph of cerium(III) ultraphosphate, CeP(5)O(14)
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title_sort | orthorhombic polymorph of cerium(iii) ultraphosphate, cep(5)o(14) |
topic | Inorganic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959646/ https://www.ncbi.nlm.nih.gov/pubmed/21580810 http://dx.doi.org/10.1107/S1600536808032972 |
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