1-Cyclo­pentyl­idene-2-(2,4-dinitro­phenyl)­hydrazine

The title compound, C(11)H(12)N(4)O(4), was synthesized by the reaction of (2,4-dinitro­phen­yl)hydrazine with cyclo­penta­none. The cyclo­pentyl fragment is disordered over two sites with occupancies of 0.63 (1) and 0.37 (1). An intra­molecular N—H⋯O hydrogen bond helps to establish the conformatio...

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Detalles Bibliográficos
Autores principales: Ji, Ning-Ning, Shi, Zhi-Qiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959650/
https://www.ncbi.nlm.nih.gov/pubmed/21581001
http://dx.doi.org/10.1107/S1600536808033345
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author Ji, Ning-Ning
Shi, Zhi-Qiang
author_facet Ji, Ning-Ning
Shi, Zhi-Qiang
author_sort Ji, Ning-Ning
collection PubMed
description The title compound, C(11)H(12)N(4)O(4), was synthesized by the reaction of (2,4-dinitro­phen­yl)hydrazine with cyclo­penta­none. The cyclo­pentyl fragment is disordered over two sites with occupancies of 0.63 (1) and 0.37 (1). An intra­molecular N—H⋯O hydrogen bond helps to establish the conformation. Pairs of mol­ecules are held together by π–π inter­actions between adjacent benzene rings [centroid-to-centroid distance 3.589 (2) Å].
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spelling pubmed-29596502010-12-30 1-Cyclo­pentyl­idene-2-(2,4-dinitro­phenyl)­hydrazine Ji, Ning-Ning Shi, Zhi-Qiang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(12)N(4)O(4), was synthesized by the reaction of (2,4-dinitro­phen­yl)hydrazine with cyclo­penta­none. The cyclo­pentyl fragment is disordered over two sites with occupancies of 0.63 (1) and 0.37 (1). An intra­molecular N—H⋯O hydrogen bond helps to establish the conformation. Pairs of mol­ecules are held together by π–π inter­actions between adjacent benzene rings [centroid-to-centroid distance 3.589 (2) Å]. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959650/ /pubmed/21581001 http://dx.doi.org/10.1107/S1600536808033345 Text en © Ji and Shi 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ji, Ning-Ning
Shi, Zhi-Qiang
1-Cyclo­pentyl­idene-2-(2,4-dinitro­phenyl)­hydrazine
title 1-Cyclo­pentyl­idene-2-(2,4-dinitro­phenyl)­hydrazine
title_full 1-Cyclo­pentyl­idene-2-(2,4-dinitro­phenyl)­hydrazine
title_fullStr 1-Cyclo­pentyl­idene-2-(2,4-dinitro­phenyl)­hydrazine
title_full_unstemmed 1-Cyclo­pentyl­idene-2-(2,4-dinitro­phenyl)­hydrazine
title_short 1-Cyclo­pentyl­idene-2-(2,4-dinitro­phenyl)­hydrazine
title_sort 1-cyclo­pentyl­idene-2-(2,4-dinitro­phenyl)­hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959650/
https://www.ncbi.nlm.nih.gov/pubmed/21581001
http://dx.doi.org/10.1107/S1600536808033345
work_keys_str_mv AT jiningning 1cyclopentylidene224dinitrophenylhydrazine
AT shizhiqiang 1cyclopentylidene224dinitrophenylhydrazine

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