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Tris(ethane-1,2-diamine-κ(2) N,N′)cobalt(II) cis-aqua-2κO-μ-cyanido-1:2κ(2) C:N-heptacyanido-1κ(7) C-bis(ethane-1,2-diamine-2κ(2) N,N′)cobalt(II)molybdenum(IV) dihydrate
The title compound, [Co(C(2)H(8)N(2))(3)][CoMo(CN)(8)(C(2)H(8)N(2))(2)(H(2)O)]·2H(2)O, is isostructural with the Ni(II) analogue. The Mo(IV) atom is coordinated by eight cyanide ligands, one of which forms a bridge to a Co(II) atom that is itself coordinated by two bidentate ethane-1,2-diamine (en)...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959651/ https://www.ncbi.nlm.nih.gov/pubmed/21580880 http://dx.doi.org/10.1107/S1600536808033564 |
| _version_ | 1782188550689652736 |
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| author | Purcell, W. Visser, Hendrik G. |
| author_facet | Purcell, W. Visser, Hendrik G. |
| author_sort | Purcell, W. |
| collection | PubMed |
| description | The title compound, [Co(C(2)H(8)N(2))(3)][CoMo(CN)(8)(C(2)H(8)N(2))(2)(H(2)O)]·2H(2)O, is isostructural with the Ni(II) analogue. The Mo(IV) atom is coordinated by eight cyanide ligands, one of which forms a bridge to a Co(II) atom that is itself coordinated by two bidentate ethane-1,2-diamine (en) ligands and one water molecule. Another Co(II) complex, coordinated to three bidentate en ligands, acts as the counter-ion. The crystal structure contains O—H⋯N/O, N—H⋯N/O and C—H⋯N/O hydrogen bonds, which form a three-dimensional network. |
| format | Text |
| id | pubmed-2959651 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29596512010-12-30 Tris(ethane-1,2-diamine-κ(2) N,N′)cobalt(II) cis-aqua-2κO-μ-cyanido-1:2κ(2) C:N-heptacyanido-1κ(7) C-bis(ethane-1,2-diamine-2κ(2) N,N′)cobalt(II)molybdenum(IV) dihydrate Purcell, W. Visser, Hendrik G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(2)H(8)N(2))(3)][CoMo(CN)(8)(C(2)H(8)N(2))(2)(H(2)O)]·2H(2)O, is isostructural with the Ni(II) analogue. The Mo(IV) atom is coordinated by eight cyanide ligands, one of which forms a bridge to a Co(II) atom that is itself coordinated by two bidentate ethane-1,2-diamine (en) ligands and one water molecule. Another Co(II) complex, coordinated to three bidentate en ligands, acts as the counter-ion. The crystal structure contains O—H⋯N/O, N—H⋯N/O and C—H⋯N/O hydrogen bonds, which form a three-dimensional network. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959651/ /pubmed/21580880 http://dx.doi.org/10.1107/S1600536808033564 Text en © Purcell and Visser 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Purcell, W. Visser, Hendrik G. Tris(ethane-1,2-diamine-κ(2) N,N′)cobalt(II) cis-aqua-2κO-μ-cyanido-1:2κ(2) C:N-heptacyanido-1κ(7) C-bis(ethane-1,2-diamine-2κ(2) N,N′)cobalt(II)molybdenum(IV) dihydrate |
| title | Tris(ethane-1,2-diamine-κ(2)
N,N′)cobalt(II) cis-aqua-2κO-μ-cyanido-1:2κ(2)
C:N-heptacyanido-1κ(7)
C-bis(ethane-1,2-diamine-2κ(2)
N,N′)cobalt(II)molybdenum(IV) dihydrate |
| title_full | Tris(ethane-1,2-diamine-κ(2)
N,N′)cobalt(II) cis-aqua-2κO-μ-cyanido-1:2κ(2)
C:N-heptacyanido-1κ(7)
C-bis(ethane-1,2-diamine-2κ(2)
N,N′)cobalt(II)molybdenum(IV) dihydrate |
| title_fullStr | Tris(ethane-1,2-diamine-κ(2)
N,N′)cobalt(II) cis-aqua-2κO-μ-cyanido-1:2κ(2)
C:N-heptacyanido-1κ(7)
C-bis(ethane-1,2-diamine-2κ(2)
N,N′)cobalt(II)molybdenum(IV) dihydrate |
| title_full_unstemmed | Tris(ethane-1,2-diamine-κ(2)
N,N′)cobalt(II) cis-aqua-2κO-μ-cyanido-1:2κ(2)
C:N-heptacyanido-1κ(7)
C-bis(ethane-1,2-diamine-2κ(2)
N,N′)cobalt(II)molybdenum(IV) dihydrate |
| title_short | Tris(ethane-1,2-diamine-κ(2)
N,N′)cobalt(II) cis-aqua-2κO-μ-cyanido-1:2κ(2)
C:N-heptacyanido-1κ(7)
C-bis(ethane-1,2-diamine-2κ(2)
N,N′)cobalt(II)molybdenum(IV) dihydrate |
| title_sort | tris(ethane-1,2-diamine-κ(2)
n,n′)cobalt(ii) cis-aqua-2κo-μ-cyanido-1:2κ(2)
c:n-heptacyanido-1κ(7)
c-bis(ethane-1,2-diamine-2κ(2)
n,n′)cobalt(ii)molybdenum(iv) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959651/ https://www.ncbi.nlm.nih.gov/pubmed/21580880 http://dx.doi.org/10.1107/S1600536808033564 |
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