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{5,5′-Bis(methoxy­carbonyl­meth­oxy)-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]­diphenolato}copper(II)

The title compound, [Cu(C(22)H(22)N(2)O(8))], is a tetra­dentate Schiff base complex. The Cu(II) ion has a nearly square-planar geometry, being coordinated by two N atoms and two O atoms. The two chemically equivalent halves of the mol­ecule are crystallographically independent. One of the carboxyli...

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Detalles Bibliográficos
Autores principales: Wang, Zhi-Hui, Ma, Jian-Fang, Wu, Hua, Liu, Hai-Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959654/
https://www.ncbi.nlm.nih.gov/pubmed/21580875
http://dx.doi.org/10.1107/S1600536808033084
Descripción
Sumario:The title compound, [Cu(C(22)H(22)N(2)O(8))], is a tetra­dentate Schiff base complex. The Cu(II) ion has a nearly square-planar geometry, being coordinated by two N atoms and two O atoms. The two chemically equivalent halves of the mol­ecule are crystallographically independent. One of the carboxylic acid methyl ester units is located in the main plane of the mol­ecule and the other is rotated by 65.3 (5)° with respect to this unit. In the crystal structure, there are π–π stacking inter­actions between adjacent six-membered chelate rings, with centroid-to-centroid distances of 3.602 (2) Å.