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But-2-enal 2,4-dinitro­phenyl­hydrazone

In the title compound, C(10)H(10)N(4)O(4), the but-2-enal chain is almost planar, the largest deviation from the mean plane being 0.013 (1) Å, and this plane makes a dihedral angle of 9.95 (24)° with the benzene ring,. Of the two nitro groups, one is twisted with respect to the benzene ring, making...

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Detalles Bibliográficos
Autores principales: Yin, Zhi-Gang, Qian, Heng-Yu, Chen, Yu-Zhen, Hu, Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959657/
https://www.ncbi.nlm.nih.gov/pubmed/21581009
http://dx.doi.org/10.1107/S1600536808033254
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author Yin, Zhi-Gang
Qian, Heng-Yu
Chen, Yu-Zhen
Hu, Jie
author_facet Yin, Zhi-Gang
Qian, Heng-Yu
Chen, Yu-Zhen
Hu, Jie
author_sort Yin, Zhi-Gang
collection PubMed
description In the title compound, C(10)H(10)N(4)O(4), the but-2-enal chain is almost planar, the largest deviation from the mean plane being 0.013 (1) Å, and this plane makes a dihedral angle of 9.95 (24)° with the benzene ring,. Of the two nitro groups, one is twisted with respect to the benzene ring, making a dihedral angle of 5.7 (1)°, whereas the other is nearly in the plane of the benzene ring, with a twist angle of only 0.7 (1)°. This difference is related to the occurence of an intra­molecular N—H⋯O hydrogen bond with the O atom of the less twisted nitro group. The NH group is also involved in a weak inter­action with the same O atom of a symmetry-related mol­ecule, thus forming a pseudo inversion dimer.
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spelling pubmed-29596572010-12-30 But-2-enal 2,4-dinitro­phenyl­hydrazone Yin, Zhi-Gang Qian, Heng-Yu Chen, Yu-Zhen Hu, Jie Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(10)N(4)O(4), the but-2-enal chain is almost planar, the largest deviation from the mean plane being 0.013 (1) Å, and this plane makes a dihedral angle of 9.95 (24)° with the benzene ring,. Of the two nitro groups, one is twisted with respect to the benzene ring, making a dihedral angle of 5.7 (1)°, whereas the other is nearly in the plane of the benzene ring, with a twist angle of only 0.7 (1)°. This difference is related to the occurence of an intra­molecular N—H⋯O hydrogen bond with the O atom of the less twisted nitro group. The NH group is also involved in a weak inter­action with the same O atom of a symmetry-related mol­ecule, thus forming a pseudo inversion dimer. International Union of Crystallography 2008-10-22 /pmc/articles/PMC2959657/ /pubmed/21581009 http://dx.doi.org/10.1107/S1600536808033254 Text en © Yin et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yin, Zhi-Gang
Qian, Heng-Yu
Chen, Yu-Zhen
Hu, Jie
But-2-enal 2,4-dinitro­phenyl­hydrazone
title But-2-enal 2,4-dinitro­phenyl­hydrazone
title_full But-2-enal 2,4-dinitro­phenyl­hydrazone
title_fullStr But-2-enal 2,4-dinitro­phenyl­hydrazone
title_full_unstemmed But-2-enal 2,4-dinitro­phenyl­hydrazone
title_short But-2-enal 2,4-dinitro­phenyl­hydrazone
title_sort but-2-enal 2,4-dinitro­phenyl­hydrazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959657/
https://www.ncbi.nlm.nih.gov/pubmed/21581009
http://dx.doi.org/10.1107/S1600536808033254
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