A new cobalt(II) complex with 5-(4-pyrid­yl)tetra­zole ligands

A new mononuclear cobalt(II) complex, tetra­aqua­bis[5-(4-pyrid­yl)tetra­zolido-κN (5)]cobalt(II) dihydrate, [Co(C(6)H(4)N(5))(2)(H(2)O)(4)]·2H(2)O, has been synthesized and structurally characterized. The Co(II) atom is coordinated by two N atoms from 5-(4-pyrid­yl)tetra­zole ligands (L), as well a...

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Detalles Bibliográficos
Autores principales: Zhu, Wei-Feng, Zhou, Xing-Fen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959662/
https://www.ncbi.nlm.nih.gov/pubmed/21580911
http://dx.doi.org/10.1107/S1600536808034880
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author Zhu, Wei-Feng
Zhou, Xing-Fen
author_facet Zhu, Wei-Feng
Zhou, Xing-Fen
author_sort Zhu, Wei-Feng
collection PubMed
description A new mononuclear cobalt(II) complex, tetra­aqua­bis[5-(4-pyrid­yl)tetra­zolido-κN (5)]cobalt(II) dihydrate, [Co(C(6)H(4)N(5))(2)(H(2)O)(4)]·2H(2)O, has been synthesized and structurally characterized. The Co(II) atom is coordinated by two N atoms from 5-(4-pyrid­yl)tetra­zole ligands (L), as well as four O atoms from coordinated water mol­ecules. The mol­ecule is centrosymmetric, with pairs of equivalent ligands lying trans to each other in a slightly distorted octa­hedral coordination geometry. A prominent feature of the complex is the formation of a three-dimensional supra­molecular network via O—H⋯O and O—H⋯N hydrogen bonds.
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spelling pubmed-29596622010-12-30 A new cobalt(II) complex with 5-(4-pyrid­yl)tetra­zole ligands Zhu, Wei-Feng Zhou, Xing-Fen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers A new mononuclear cobalt(II) complex, tetra­aqua­bis[5-(4-pyrid­yl)tetra­zolido-κN (5)]cobalt(II) dihydrate, [Co(C(6)H(4)N(5))(2)(H(2)O)(4)]·2H(2)O, has been synthesized and structurally characterized. The Co(II) atom is coordinated by two N atoms from 5-(4-pyrid­yl)tetra­zole ligands (L), as well as four O atoms from coordinated water mol­ecules. The mol­ecule is centrosymmetric, with pairs of equivalent ligands lying trans to each other in a slightly distorted octa­hedral coordination geometry. A prominent feature of the complex is the formation of a three-dimensional supra­molecular network via O—H⋯O and O—H⋯N hydrogen bonds. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959662/ /pubmed/21580911 http://dx.doi.org/10.1107/S1600536808034880 Text en © Zhu and Zhou 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Wei-Feng
Zhou, Xing-Fen
A new cobalt(II) complex with 5-(4-pyrid­yl)tetra­zole ligands
title A new cobalt(II) complex with 5-(4-pyrid­yl)tetra­zole ligands
title_full A new cobalt(II) complex with 5-(4-pyrid­yl)tetra­zole ligands
title_fullStr A new cobalt(II) complex with 5-(4-pyrid­yl)tetra­zole ligands
title_full_unstemmed A new cobalt(II) complex with 5-(4-pyrid­yl)tetra­zole ligands
title_short A new cobalt(II) complex with 5-(4-pyrid­yl)tetra­zole ligands
title_sort new cobalt(ii) complex with 5-(4-pyrid­yl)tetra­zole ligands
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959662/
https://www.ncbi.nlm.nih.gov/pubmed/21580911
http://dx.doi.org/10.1107/S1600536808034880
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