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2,7-Dibromo-9-octyl-9H-carbazole
In the crystal structure of the title compound, C(20)H(23)Br(2)N, the octyl chains are extended in an anti conformation and form a segregating bilayer, isolating rows of carbazole units. The carbazole moieties are engaged in offset π–π interactions; the smallest centroid-to-centroid distance is 4.2...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959667/ https://www.ncbi.nlm.nih.gov/pubmed/21581007 http://dx.doi.org/10.1107/S1600536808032121 |
Sumario: | In the crystal structure of the title compound, C(20)H(23)Br(2)N, the octyl chains are extended in an anti conformation and form a segregating bilayer, isolating rows of carbazole units. The carbazole moieties are engaged in offset π–π interactions; the smallest centroid-to-centroid distance is 4.2822 (11) Å. This offset packing motif allows the methylene group attached directly to the N atom to be involved in two short C—H⋯π interactions (H⋯centroid distances = 2.96 and 2.99 Å) with an adjacent carbazole. One of the Br atoms also participates in a short contact [3.5475 (3) Å] with a symmetry-related (−x, 1 − y, −z) Br atom. This value is significantly smaller than the sum of the van der Waals radii for bromine (3.70 Å). |
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