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2,7-Dibromo-9-octyl-9H-carbazole
In the crystal structure of the title compound, C(20)H(23)Br(2)N, the octyl chains are extended in an anti conformation and form a segregating bilayer, isolating rows of carbazole units. The carbazole moieties are engaged in offset π–π interactions; the smallest centroid-to-centroid distance is 4.2...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959667/ https://www.ncbi.nlm.nih.gov/pubmed/21581007 http://dx.doi.org/10.1107/S1600536808032121 |
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author | Gagnon, Eric Laliberté, Dominic |
author_facet | Gagnon, Eric Laliberté, Dominic |
author_sort | Gagnon, Eric |
collection | PubMed |
description | In the crystal structure of the title compound, C(20)H(23)Br(2)N, the octyl chains are extended in an anti conformation and form a segregating bilayer, isolating rows of carbazole units. The carbazole moieties are engaged in offset π–π interactions; the smallest centroid-to-centroid distance is 4.2822 (11) Å. This offset packing motif allows the methylene group attached directly to the N atom to be involved in two short C—H⋯π interactions (H⋯centroid distances = 2.96 and 2.99 Å) with an adjacent carbazole. One of the Br atoms also participates in a short contact [3.5475 (3) Å] with a symmetry-related (−x, 1 − y, −z) Br atom. This value is significantly smaller than the sum of the van der Waals radii for bromine (3.70 Å). |
format | Text |
id | pubmed-2959667 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29596672010-12-30 2,7-Dibromo-9-octyl-9H-carbazole Gagnon, Eric Laliberté, Dominic Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(20)H(23)Br(2)N, the octyl chains are extended in an anti conformation and form a segregating bilayer, isolating rows of carbazole units. The carbazole moieties are engaged in offset π–π interactions; the smallest centroid-to-centroid distance is 4.2822 (11) Å. This offset packing motif allows the methylene group attached directly to the N atom to be involved in two short C—H⋯π interactions (H⋯centroid distances = 2.96 and 2.99 Å) with an adjacent carbazole. One of the Br atoms also participates in a short contact [3.5475 (3) Å] with a symmetry-related (−x, 1 − y, −z) Br atom. This value is significantly smaller than the sum of the van der Waals radii for bromine (3.70 Å). International Union of Crystallography 2008-10-22 /pmc/articles/PMC2959667/ /pubmed/21581007 http://dx.doi.org/10.1107/S1600536808032121 Text en © Gagnon and Laliberté 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gagnon, Eric Laliberté, Dominic 2,7-Dibromo-9-octyl-9H-carbazole |
title | 2,7-Dibromo-9-octyl-9H-carbazole |
title_full | 2,7-Dibromo-9-octyl-9H-carbazole |
title_fullStr | 2,7-Dibromo-9-octyl-9H-carbazole |
title_full_unstemmed | 2,7-Dibromo-9-octyl-9H-carbazole |
title_short | 2,7-Dibromo-9-octyl-9H-carbazole |
title_sort | 2,7-dibromo-9-octyl-9h-carbazole |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959667/ https://www.ncbi.nlm.nih.gov/pubmed/21581007 http://dx.doi.org/10.1107/S1600536808032121 |
work_keys_str_mv | AT gagnoneric 27dibromo9octyl9hcarbazole AT lalibertedominic 27dibromo9octyl9hcarbazole |