Dichlorido[2,2′-(oxydimethyl­ene)dipyridine]copper(II)

In the title complex, [CuCl(2)(C(12)H(12)N(2)O)], the Cu(II) ion is coordinated in a distorted trigonal-bipyramidal environment. In the crystal structure, there is a weak π–π stacking inter­action between symmetry-related pyridine rings, with a centroid-to-centroid distance of 3.8134 (17) Å. In addi...

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Detalles Bibliográficos
Autor principal: Li, Jin Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959670/
https://www.ncbi.nlm.nih.gov/pubmed/21580904
http://dx.doi.org/10.1107/S1600536808034612
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author Li, Jin Min
author_facet Li, Jin Min
author_sort Li, Jin Min
collection PubMed
description In the title complex, [CuCl(2)(C(12)H(12)N(2)O)], the Cu(II) ion is coordinated in a distorted trigonal-bipyramidal environment. In the crystal structure, there is a weak π–π stacking inter­action between symmetry-related pyridine rings, with a centroid-to-centroid distance of 3.8134 (17) Å. In addition, there is relatively close contact between the pyridine ring π-system and a symmetry-related Cu(II) ion (Cu⋯centroid distance of 3.868 Å).
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spelling pubmed-29596702010-12-30 Dichlorido[2,2′-(oxydimethyl­ene)dipyridine]copper(II) Li, Jin Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(12)H(12)N(2)O)], the Cu(II) ion is coordinated in a distorted trigonal-bipyramidal environment. In the crystal structure, there is a weak π–π stacking inter­action between symmetry-related pyridine rings, with a centroid-to-centroid distance of 3.8134 (17) Å. In addition, there is relatively close contact between the pyridine ring π-system and a symmetry-related Cu(II) ion (Cu⋯centroid distance of 3.868 Å). International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959670/ /pubmed/21580904 http://dx.doi.org/10.1107/S1600536808034612 Text en © Jin Min Li 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Jin Min
Dichlorido[2,2′-(oxydimethyl­ene)dipyridine]copper(II)
title Dichlorido[2,2′-(oxydimethyl­ene)dipyridine]copper(II)
title_full Dichlorido[2,2′-(oxydimethyl­ene)dipyridine]copper(II)
title_fullStr Dichlorido[2,2′-(oxydimethyl­ene)dipyridine]copper(II)
title_full_unstemmed Dichlorido[2,2′-(oxydimethyl­ene)dipyridine]copper(II)
title_short Dichlorido[2,2′-(oxydimethyl­ene)dipyridine]copper(II)
title_sort dichlorido[2,2′-(oxydimethyl­ene)dipyridine]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959670/
https://www.ncbi.nlm.nih.gov/pubmed/21580904
http://dx.doi.org/10.1107/S1600536808034612
work_keys_str_mv AT lijinmin dichlorido22oxydimethylenedipyridinecopperii

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