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(±)-Cyclohexane-1,2-diyl bis(4-nitrobenzoate)
The crystal structure of the title compound, C(20)H(18)N(2)O(8), has been investigated to establish the relative stereochemistry between the ester groups. The cyclohexane ring adopts a chair conformation, in which the two ester groups occupy the adjacent equatorial positions in a trans relationship...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959677/ https://www.ncbi.nlm.nih.gov/pubmed/21581034 http://dx.doi.org/10.1107/S1600536808033874 |
Sumario: | The crystal structure of the title compound, C(20)H(18)N(2)O(8), has been investigated to establish the relative stereochemistry between the ester groups. The cyclohexane ring adopts a chair conformation, in which the two ester groups occupy the adjacent equatorial positions in a trans relationship with each other. The molecules assemble in the crystal as chains along the c axis via C—H⋯π interactions between the cyclohexane ring and a pair of nitrophenyl rings of the neighbouring molecule. Also observed are π–π stacking interactions between the nitrophenyl rings of neighbouring chains, with a perpendicular distance between these rings of 3.409 Å and a slippage of 0.969 Å. |
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