8-Iodo­quinolinium triiodide tetra­hydro­furan solvate

The title compound, C(9)H(7)IN(+)·I(3) (−)·C(4)H(8)O, was synthesized from 8-amino­quinoline using the Sandmeyer reaction. The 8-iodo­quinolinium cation is essentially planar and the triiodide ion is almost linear. N—H⋯O hydrogen bonds, and inter­molecular I⋯I [3.7100 (5) Å] and I⋯H inter­actions, b...

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Detalles Bibliográficos
Autores principales: Son, Jung-Ho, Hoefelmeyer, James D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959684/
https://www.ncbi.nlm.nih.gov/pubmed/21580942
http://dx.doi.org/10.1107/S1600536808031516
Descripción
Sumario:The title compound, C(9)H(7)IN(+)·I(3) (−)·C(4)H(8)O, was synthesized from 8-amino­quinoline using the Sandmeyer reaction. The 8-iodo­quinolinium cation is essentially planar and the triiodide ion is almost linear. N—H⋯O hydrogen bonds, and inter­molecular I⋯I [3.7100 (5) Å] and I⋯H inter­actions, between the cation, anion and solvent mol­ecules result in the formation of sheets oriented parallel to the ([Image: see text]03) plane. Between the sheets, 8-iodo­quinolinium and triiodide ions are stacked alternately, with I⋯C distances in the range ∼3.8–4.0 Å.

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