8-Iodo­quinolinium triiodide tetra­hydro­furan solvate

The title compound, C(9)H(7)IN(+)·I(3) (−)·C(4)H(8)O, was synthesized from 8-amino­quinoline using the Sandmeyer reaction. The 8-iodo­quinolinium cation is essentially planar and the triiodide ion is almost linear. N—H⋯O hydrogen bonds, and inter­molecular I⋯I [3.7100 (5) Å] and I⋯H inter­actions, b...

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Detalles Bibliográficos
Autores principales: Son, Jung-Ho, Hoefelmeyer, James D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959684/
https://www.ncbi.nlm.nih.gov/pubmed/21580942
http://dx.doi.org/10.1107/S1600536808031516
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author Son, Jung-Ho
Hoefelmeyer, James D.
author_facet Son, Jung-Ho
Hoefelmeyer, James D.
author_sort Son, Jung-Ho
collection PubMed
description The title compound, C(9)H(7)IN(+)·I(3) (−)·C(4)H(8)O, was synthesized from 8-amino­quinoline using the Sandmeyer reaction. The 8-iodo­quinolinium cation is essentially planar and the triiodide ion is almost linear. N—H⋯O hydrogen bonds, and inter­molecular I⋯I [3.7100 (5) Å] and I⋯H inter­actions, between the cation, anion and solvent mol­ecules result in the formation of sheets oriented parallel to the ([Image: see text]03) plane. Between the sheets, 8-iodo­quinolinium and triiodide ions are stacked alternately, with I⋯C distances in the range ∼3.8–4.0 Å.
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spelling pubmed-29596842010-12-30 8-Iodo­quinolinium triiodide tetra­hydro­furan solvate Son, Jung-Ho Hoefelmeyer, James D. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(7)IN(+)·I(3) (−)·C(4)H(8)O, was synthesized from 8-amino­quinoline using the Sandmeyer reaction. The 8-iodo­quinolinium cation is essentially planar and the triiodide ion is almost linear. N—H⋯O hydrogen bonds, and inter­molecular I⋯I [3.7100 (5) Å] and I⋯H inter­actions, between the cation, anion and solvent mol­ecules result in the formation of sheets oriented parallel to the ([Image: see text]03) plane. Between the sheets, 8-iodo­quinolinium and triiodide ions are stacked alternately, with I⋯C distances in the range ∼3.8–4.0 Å. International Union of Crystallography 2008-10-04 /pmc/articles/PMC2959684/ /pubmed/21580942 http://dx.doi.org/10.1107/S1600536808031516 Text en © Son and Hoefelmeyer 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Son, Jung-Ho
Hoefelmeyer, James D.
8-Iodo­quinolinium triiodide tetra­hydro­furan solvate
title 8-Iodo­quinolinium triiodide tetra­hydro­furan solvate
title_full 8-Iodo­quinolinium triiodide tetra­hydro­furan solvate
title_fullStr 8-Iodo­quinolinium triiodide tetra­hydro­furan solvate
title_full_unstemmed 8-Iodo­quinolinium triiodide tetra­hydro­furan solvate
title_short 8-Iodo­quinolinium triiodide tetra­hydro­furan solvate
title_sort 8-iodo­quinolinium triiodide tetra­hydro­furan solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959684/
https://www.ncbi.nlm.nih.gov/pubmed/21580942
http://dx.doi.org/10.1107/S1600536808031516
work_keys_str_mv AT sonjungho 8iodoquinoliniumtriiodidetetrahydrofuransolvate
AT hoefelmeyerjamesd 8iodoquinoliniumtriiodidetetrahydrofuransolvate

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