Diethyl­enetriaminium hexa­fluorido­titanate(IV) fluoride

The title compound, (C(6)H(21)N(4))[TiF(6)]F, was synthesized by the reaction of TiO(2), tris­(2-amino­ethyl)amine, HF and ethanol at 463 K in a microwave oven. The crystal structure consists of two crystallographically independent [TiF(6)](2−) anions, two fluoride anions and two triply-protonated t...

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Detalles Bibliográficos
Autores principales: Lhoste, J., Adil, K., Leblanc, M., Maisonneuve, V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959685/
https://www.ncbi.nlm.nih.gov/pubmed/21580831
http://dx.doi.org/10.1107/S1600536808009781
Descripción
Sumario:The title compound, (C(6)H(21)N(4))[TiF(6)]F, was synthesized by the reaction of TiO(2), tris­(2-amino­ethyl)amine, HF and ethanol at 463 K in a microwave oven. The crystal structure consists of two crystallographically independent [TiF(6)](2−) anions, two fluoride anions and two triply-protonated tris­(2-amino­ethyl)­amine cations. The Ti atoms are coordinated by six F atoms within slightly distorted octa­hedra. The anions and cations are connected by inter­molecular N—H⋯F hydrogen bonds.

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