Diethyl­enetriaminium hexa­fluorido­titanate(IV) fluoride

The title compound, (C(6)H(21)N(4))[TiF(6)]F, was synthesized by the reaction of TiO(2), tris­(2-amino­ethyl)amine, HF and ethanol at 463 K in a microwave oven. The crystal structure consists of two crystallographically independent [TiF(6)](2−) anions, two fluoride anions and two triply-protonated t...

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Detalles Bibliográficos
Autores principales: Lhoste, J., Adil, K., Leblanc, M., Maisonneuve, V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959685/
https://www.ncbi.nlm.nih.gov/pubmed/21580831
http://dx.doi.org/10.1107/S1600536808009781
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author Lhoste, J.
Adil, K.
Leblanc, M.
Maisonneuve, V.
author_facet Lhoste, J.
Adil, K.
Leblanc, M.
Maisonneuve, V.
author_sort Lhoste, J.
collection PubMed
description The title compound, (C(6)H(21)N(4))[TiF(6)]F, was synthesized by the reaction of TiO(2), tris­(2-amino­ethyl)amine, HF and ethanol at 463 K in a microwave oven. The crystal structure consists of two crystallographically independent [TiF(6)](2−) anions, two fluoride anions and two triply-protonated tris­(2-amino­ethyl)­amine cations. The Ti atoms are coordinated by six F atoms within slightly distorted octa­hedra. The anions and cations are connected by inter­molecular N—H⋯F hydrogen bonds.
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spelling pubmed-29596852010-12-30 Diethyl­enetriaminium hexa­fluorido­titanate(IV) fluoride Lhoste, J. Adil, K. Leblanc, M. Maisonneuve, V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(6)H(21)N(4))[TiF(6)]F, was synthesized by the reaction of TiO(2), tris­(2-amino­ethyl)amine, HF and ethanol at 463 K in a microwave oven. The crystal structure consists of two crystallographically independent [TiF(6)](2−) anions, two fluoride anions and two triply-protonated tris­(2-amino­ethyl)­amine cations. The Ti atoms are coordinated by six F atoms within slightly distorted octa­hedra. The anions and cations are connected by inter­molecular N—H⋯F hydrogen bonds. International Union of Crystallography 2008-10-09 /pmc/articles/PMC2959685/ /pubmed/21580831 http://dx.doi.org/10.1107/S1600536808009781 Text en © Lhoste et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lhoste, J.
Adil, K.
Leblanc, M.
Maisonneuve, V.
Diethyl­enetriaminium hexa­fluorido­titanate(IV) fluoride
title Diethyl­enetriaminium hexa­fluorido­titanate(IV) fluoride
title_full Diethyl­enetriaminium hexa­fluorido­titanate(IV) fluoride
title_fullStr Diethyl­enetriaminium hexa­fluorido­titanate(IV) fluoride
title_full_unstemmed Diethyl­enetriaminium hexa­fluorido­titanate(IV) fluoride
title_short Diethyl­enetriaminium hexa­fluorido­titanate(IV) fluoride
title_sort diethyl­enetriaminium hexa­fluorido­titanate(iv) fluoride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959685/
https://www.ncbi.nlm.nih.gov/pubmed/21580831
http://dx.doi.org/10.1107/S1600536808009781
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