Bis(4,4′-methyl­enedicyclo­hexyl­aminium) μ-benzene-1,4-dicarboxyl­ato-bis­[tri­chlorido­zinc(II)] tetra­hydrate

The title compound, (C(13)H(28)N(2))(2)[Zn(2)(C(8)H(4)O(4))Cl(6)]·4H(2)O, was prepared by the reaction of ZnCl(2)·6H(2)O, benzene-1,4-dicarboxylic acid and 4,4′-diamino­dicyclo­hexyl­methane in methanol. The [Zn(2)Cl(6)(C(8)H(4)O(4))](4−) anions lie on centres of inversion and comprise two ZnCl(3) g...

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Autores principales: Hsu, Chen-Yen, Yeh, Chun-Wei, Wu, Chi-Phi, Lin, Chia-Her, Chen, Jhy-Der
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959686/
https://www.ncbi.nlm.nih.gov/pubmed/21580861
http://dx.doi.org/10.1107/S1600536808033011
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author Hsu, Chen-Yen
Yeh, Chun-Wei
Wu, Chi-Phi
Lin, Chia-Her
Chen, Jhy-Der
author_facet Hsu, Chen-Yen
Yeh, Chun-Wei
Wu, Chi-Phi
Lin, Chia-Her
Chen, Jhy-Der
author_sort Hsu, Chen-Yen
collection PubMed
description The title compound, (C(13)H(28)N(2))(2)[Zn(2)(C(8)H(4)O(4))Cl(6)]·4H(2)O, was prepared by the reaction of ZnCl(2)·6H(2)O, benzene-1,4-dicarboxylic acid and 4,4′-diamino­dicyclo­hexyl­methane in methanol. The [Zn(2)Cl(6)(C(8)H(4)O(4))](4−) anions lie on centres of inversion and comprise two ZnCl(3) groups bridged by benzene-1,4-dicarboxyl­ate. In addition to N—H⋯Cl and N—H⋯O hydrogen bonds between the cations and anions, solvent water mol­ecules form O—H⋯O and O—H⋯Cl hydrogen bonds to give a three-dimensional network.
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spelling pubmed-29596862010-12-30 Bis(4,4′-methyl­enedicyclo­hexyl­aminium) μ-benzene-1,4-dicarboxyl­ato-bis­[tri­chlorido­zinc(II)] tetra­hydrate Hsu, Chen-Yen Yeh, Chun-Wei Wu, Chi-Phi Lin, Chia-Her Chen, Jhy-Der Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(13)H(28)N(2))(2)[Zn(2)(C(8)H(4)O(4))Cl(6)]·4H(2)O, was prepared by the reaction of ZnCl(2)·6H(2)O, benzene-1,4-dicarboxylic acid and 4,4′-diamino­dicyclo­hexyl­methane in methanol. The [Zn(2)Cl(6)(C(8)H(4)O(4))](4−) anions lie on centres of inversion and comprise two ZnCl(3) groups bridged by benzene-1,4-dicarboxyl­ate. In addition to N—H⋯Cl and N—H⋯O hydrogen bonds between the cations and anions, solvent water mol­ecules form O—H⋯O and O—H⋯Cl hydrogen bonds to give a three-dimensional network. International Union of Crystallography 2008-10-15 /pmc/articles/PMC2959686/ /pubmed/21580861 http://dx.doi.org/10.1107/S1600536808033011 Text en © Hsu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hsu, Chen-Yen
Yeh, Chun-Wei
Wu, Chi-Phi
Lin, Chia-Her
Chen, Jhy-Der
Bis(4,4′-methyl­enedicyclo­hexyl­aminium) μ-benzene-1,4-dicarboxyl­ato-bis­[tri­chlorido­zinc(II)] tetra­hydrate
title Bis(4,4′-methyl­enedicyclo­hexyl­aminium) μ-benzene-1,4-dicarboxyl­ato-bis­[tri­chlorido­zinc(II)] tetra­hydrate
title_full Bis(4,4′-methyl­enedicyclo­hexyl­aminium) μ-benzene-1,4-dicarboxyl­ato-bis­[tri­chlorido­zinc(II)] tetra­hydrate
title_fullStr Bis(4,4′-methyl­enedicyclo­hexyl­aminium) μ-benzene-1,4-dicarboxyl­ato-bis­[tri­chlorido­zinc(II)] tetra­hydrate
title_full_unstemmed Bis(4,4′-methyl­enedicyclo­hexyl­aminium) μ-benzene-1,4-dicarboxyl­ato-bis­[tri­chlorido­zinc(II)] tetra­hydrate
title_short Bis(4,4′-methyl­enedicyclo­hexyl­aminium) μ-benzene-1,4-dicarboxyl­ato-bis­[tri­chlorido­zinc(II)] tetra­hydrate
title_sort bis(4,4′-methyl­enedicyclo­hexyl­aminium) μ-benzene-1,4-dicarboxyl­ato-bis­[tri­chlorido­zinc(ii)] tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959686/
https://www.ncbi.nlm.nih.gov/pubmed/21580861
http://dx.doi.org/10.1107/S1600536808033011
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