Poly[μ-4,4′-bipyridine-κ(2) N:N′-μ-thio­cyanato-κ(2) N:S-copper(I)]

In the crystal structure of the title compound, [Cu(NCS)(C(10)H(8)N(2))](n), the Cu(I) atom is coordinated by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) ligands and one N and one S atom from two symmetry-related thio­cyanate ligands in a distorted tetra­hedral environment. The thio...

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Detalles Bibliográficos
Autores principales: Wriedt, Mario, Sellmer, Sina, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959690/
https://www.ncbi.nlm.nih.gov/pubmed/21580869
http://dx.doi.org/10.1107/S1600536808033175
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author Wriedt, Mario
Sellmer, Sina
Näther, Christian
author_facet Wriedt, Mario
Sellmer, Sina
Näther, Christian
author_sort Wriedt, Mario
collection PubMed
description In the crystal structure of the title compound, [Cu(NCS)(C(10)H(8)N(2))](n), the Cu(I) atom is coordinated by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) ligands and one N and one S atom from two symmetry-related thio­cyanate ligands in a distorted tetra­hedral environment. The thio­cyanate ligands bridge the Cu(I) atoms into a zigzag [CuSCN](n) chain running parallel to the a axis. These chains are further connected through two bipy ligands that bridge the Cu(I) centers to generate a two-dimensional brick-like network. The pyridyl planes of the ligands exhibit a dihedral angle of 37.35 (12)°.
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spelling pubmed-29596902010-12-30 Poly[μ-4,4′-bipyridine-κ(2) N:N′-μ-thio­cyanato-κ(2) N:S-copper(I)] Wriedt, Mario Sellmer, Sina Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(NCS)(C(10)H(8)N(2))](n), the Cu(I) atom is coordinated by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) ligands and one N and one S atom from two symmetry-related thio­cyanate ligands in a distorted tetra­hedral environment. The thio­cyanate ligands bridge the Cu(I) atoms into a zigzag [CuSCN](n) chain running parallel to the a axis. These chains are further connected through two bipy ligands that bridge the Cu(I) centers to generate a two-dimensional brick-like network. The pyridyl planes of the ligands exhibit a dihedral angle of 37.35 (12)°. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959690/ /pubmed/21580869 http://dx.doi.org/10.1107/S1600536808033175 Text en © Wriedt et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wriedt, Mario
Sellmer, Sina
Näther, Christian
Poly[μ-4,4′-bipyridine-κ(2) N:N′-μ-thio­cyanato-κ(2) N:S-copper(I)]
title Poly[μ-4,4′-bipyridine-κ(2) N:N′-μ-thio­cyanato-κ(2) N:S-copper(I)]
title_full Poly[μ-4,4′-bipyridine-κ(2) N:N′-μ-thio­cyanato-κ(2) N:S-copper(I)]
title_fullStr Poly[μ-4,4′-bipyridine-κ(2) N:N′-μ-thio­cyanato-κ(2) N:S-copper(I)]
title_full_unstemmed Poly[μ-4,4′-bipyridine-κ(2) N:N′-μ-thio­cyanato-κ(2) N:S-copper(I)]
title_short Poly[μ-4,4′-bipyridine-κ(2) N:N′-μ-thio­cyanato-κ(2) N:S-copper(I)]
title_sort poly[μ-4,4′-bipyridine-κ(2) n:n′-μ-thio­cyanato-κ(2) n:s-copper(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959690/
https://www.ncbi.nlm.nih.gov/pubmed/21580869
http://dx.doi.org/10.1107/S1600536808033175
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